The VCO stretching frequency of coordinated CO is lower than that of free CO
The stretching frequency of coordinated CO (carbonyl ligand) in a metal complex is typically lower than that of free CO, which has a frequency of 2310 cm^-1. The difference can be explained in terms of bonding interactions between the metal and CO ligand.
In a metal-CO complex, there are two primary bonding interactions between the metal and the carbonyl ligand: sigma and pi bonding. The sigma bond is formed by the overlap of the metal's empty d-orbital with the filled carbon-oxygen sigma orbital of the CO ligand. This interaction leads to a donation of electron density from the CO ligand to the metal.
The pi bond, on the other hand, is formed by the back-donation of electron density from the metal's filled d-orbital to the empty carbon-oxygen pi* anti-bonding orbital of the CO ligand. This back-donation weakens the C-O bond in the coordinated CO, causing a reduction in the stretching frequency compared to free CO.
So, in summary, the VCO stretching frequency of coordinated CO is lower than that of free CO (2310 cm^-1) due to the combined effect of sigma bonding and pi back-bonding between the metal and the CO ligand.
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mixing calcium chlorine with water is a chemical or physical change?
Answer:
Physical Change
Explanation:
URGENT PLEASE HELP NOW!!
When do most ionic bonds form, based on this Periodic Table?
when elements from B bond with themselves
when elements from A bond with elements from B
when elements from C bond with elements from D
when elements from A bond with themselves
Answer:
when elements from A bond with elements from B
Explanation:
The elements in part A are metals and that of B are non-metals. Ionic bonds are formed between metals and non-metals. Thus option b is correct.
What is ionic bonding?An ionic bond is formed between a metal and non-metal through loss of electron from the metal to the non-metal. Metals are electron rich and easily loss electrons.
Non-metals are electronegative and they are electron -deficient. They need to gain electrons to attain stability. Therefore non-metals such as oxygen, nitrogen, carbon etc. bonds with metals by gaining electrons from metals.
The positive charge of metal acquired by loss of electron and negative charge of nonmetals acquired by gain of electron attracts electrostatically and form the ionic bond.
The elements from A thus bonds ionically with elements from B.
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Calculate the standard reaction enthalpy for the reaction below:
3Fe2O3(s) → 2Fe3O4(s) + ½O2(g)
The standard reaction enthalpy (ΔH°) for the given reaction is 235.8 kJ/mol.
The standard enthalpies of formation (H°f) of the associated reactants and products must be taken into account in order to get the standard reaction enthalpy (H°) for the given reaction.
The balanced equation is:
3Fe₂O₃(s) → 2Fe3O₄(s) + ½O₂(g)
The standard enthalpy of formation values for Fe2O3(s), Fe3O4(s), and O2(g) are required.
The values are:
ΔH°f(Fe₂O₃) = -824.2 kJ/mol
ΔH°f(Fe3O₄) = -1118.4 kJ/mol
ΔH°f(O₂) = 0 kJ/mol
Now, find the standard reaction enthalpy by using equation:
ΔH° = ΣnΔH°f(products) - ΣnΔH°f(reactants)
In which n is the stoichiometric coefficient of each substance.
Place the values, to get:
ΔH° = [2ΔH°f(Fe3O₄) + ½ΔH°f(O2)] - [3ΔH°f(Fe₂O₃)]
ΔH° = [2(-1118.4 kJ/mol) + ½(0 kJ/mol)] - [3(-824.2 kJ/mol)]
ΔH° = [-2236.8 kJ/mol] - [-2472.6 kJ/mol]
ΔH° = -2236.8 kJ/mol + 2472.6 kJ/mol
ΔH° = 235.8 kJ/mol
Thus, the standard reaction enthalpy (ΔH°) for the given reaction is 235.8 kJ/mol.
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Models can be used to make predictions .
truth or false ?
Answer:
true
...................
True or False: The relative concentrations of ATP and ADP control the cellular rates of the citric acid cycle
True. The relative concentrations of ATP and ADP play a critical role in controlling the cellular rates of the citric acid cycle, also known as the Krebs cycle or the tricarboxylic acid (TCA) cycle.
The citric acid cycle is a series of reactions that occur in the mitochondria and generates energy by oxidizing acetyl-CoA. This energy is stored in the form of ATP, which is used to power various cellular processes.
When the cellular ATP levels are high, the rate of the citric acid cycle slows down because the cell has sufficient energy and does not need to produce more. On the other hand, when the cellular ATP levels are low, the rate of the citric acid cycle increases to produce more ATP.
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How many moles of hydrochloric acid does
1.505x10^24 atoms of hydrochloric acid make?
Answer:
2.499 mol HCl
General Formulas and Concepts:
Chemistry - Atomic Structure
Using Dimensional AnalysisAvogadro's Number - 6.022 × 10²³ atoms, molecules, formula units, etc.Explanation:
Step 1: Define
1.505 × 10²⁴ atoms HCl (Hydrochloric acid)
Step 2: Identify Conversions
Avogadro's Number
Step 3: Convert
\(1.505 \cdot 10^{24} \ atoms \ HCl(\frac{1 \ mol \ HCl}{6.022 \cdot 10^{23} \ atoms \ HCl} )\) = 2.49917 mol HCl
Step 4: Check
We are given 4 sig figs. Follow sig fig rules and round.
2.49917 mol HCl ≈ 2.499 mol HCl
During an investigation, a group of students poured two clear
liquids into a plastic zip top bag. One student placed a
thermometer in the bag to record the temperature and sealed
the bag around the thermometer. Another student gently
kneaded the bag for 10 seconds to mix the liquids. The students
observed the bag for two minutes and recorded their
observations.
Observations:
o The bag began to inflate.
o A white solid material collected at the bottom of the bag.
o The gas released from the bag had a faint sour odor.
o The temperature did not change.
Which of the students' observations does NOT provide evidence
that a chemical change has occurred?
The students' observations does not provide evidence that a chemical change has occurred is d. The temperature did not change.
While some chemical reactions may result in a temperature change, not all do. Additionally, physical changes, such as mixing two liquids or a gas being released, can occur without any change in temperature. The other observations listed, including the inflation of the bag, the formation of a white solid material, and the release of a faint sour odor, may all indicate that a chemical change has occurred.
For example, the formation of a solid material could suggest that a new substance has been formed, while the release of a gas and a change in appearance (inflation of the bag) may also indicate a chemical reaction. Overall, it is important to consider all observations and conduct further tests to confirm whether a chemical change has occurred. So therefore the correct answer is d. The temperature did not change, is the students' observations does not provide evidence that a chemical change has occurred.
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The following are halogens except
a. fluorine
b. iodine
c. chlorine
d. phenol
Answer:
i think this is [d. phenol]
The correct answer:
Phenol
\( \large{ \boxed{ \bf{ \color{green}{Option \: D}}}}\)
Phenol is a compound, While other are elments found under the 17th group, and popularly known as Halogens.
Explore more:-The name halogen comes from the Greek words "hals", meaning "salt", and "gen", meaning "to make."The halogens are a group of elements in the periodic table. They are located to the right of the other nonmetals and to the left of the noble gases.The halogens include the five elements fluorine, chlorine, bromine, iodine, and astatine. They make up column 17 of the periodic table.They have seven valence electrons in their outer shell.They all exist as diatomic molecules (two atoms) when in their pure form.Simple compounds that contain halogens are called halides.━━━━━━━━━━━━━━━━━━━━
The sum of three consecutive even numbers is 48. What are the smallest of these numbers?
Answer:
14
Explanation:
If the sum of three consecutive even numbers is 48, the smallest of these numbers is 14.
Calculate the normal freezing point of a 0.7439 mol aqueous solution of c12h22o11 that has a density of 1.35g/ml. The molal freezing point depression constant of water is 1.86 kg/mole
Answer:
Freezing point of solution = -2.740C
Explanation:
The solution is attached herewith
The normal freezing point of an aqueous solution of C₁₂H₂₂O₁₁ is -1.26°C
The freezing point depression can be calculated using the formula:
ΔTf = i* Kf*m ; where
i = van’t Hoff factorKf = freezing point depression constantm = molalility of solutionThe molality of the aqueous solution of C₁₂H₂₂O₁₁ is first determined using the formula:
molality = moles of solute/mass of water in kgThe mass of water is unknown but is determined from the mass of the solute and solution from the formula:
mass of solvent (water) = mass of solution - mass of solutemass of solute = number of moles * molar mass
moles of solute in 1 L solution = 0.7439 moles
molar mass of solute, C₁₂H₂₂O₁₁ = 342.0 g/mol
mass of solute = 0.7439 moles * 342.0 g
mass of solute = 254.41 g
mass of solution = density * volume
volume of solution = 1 L = 1000 mL
mass of solution = 1.35g/ml * 1000 mL
mass of solution = 1350 g
Therefore, mass of solvent (water) = 1350 g - 254.41 g
mass of solvent (water) = 1095.59 g
mass of solvent (water) in kg = 1095.59 g * 1 kg/ 1000 g
mass of solvent (water) in kg = 1.0956Kg
Thus, molality of solution = 0.7439 moles / 1.0956 Kg
molality of solution = 0.679 mol/kg
The freezing point depression, ΔTf, is then determined using the formula: ΔTf = i* Kf*m
Since C₁₂H₂₂O₁₁ is a non-electrolyte; i for C₁₂H₂₂O₁₁ = 1
Kf of water = 1.86 kg/mole
m = 0.679 mol/kg
ΔTf = 1 * 1.86 * 0.679
ΔTf = 1.26 °C
Therefore, freezing point depression, ΔTf = 1.26 °C
normal freezing point of solution = freezing point of water - freezing point depression
normal freezing point of solution = 0.0°C - 1.26°C
normal freezing point of solution = -1.26°C
Therefore, the normal freezing point of an aqueous solution of C₁₂H₂₂O₁₁ is -1.26°C
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Scientists predict that the human population will continue to increase will likely happen as a result?
Answer: The prediction that human population is likely to increase may result in severe problems like global warming, extinction of animals due to human activities, et cetera.
Explanation:
The human population needs resources to survive, they use the resources in such a way that it is being exploited, the trees will be cut in such a large numbers that it will affect the animals depending them.
The human population also uses fossil fuels, burning of which releases harmful gases in the environment.
The usage of technology also comes with the curse of global warming because of release of green house gases such as chlorofluorocarbon.
With an increase in human population, there can be seen many harmful effects on environment.
Answer:
whatttttttttyu[poiuytrtyuiopoiuygtfdfghjkjhgfdfghjk
Explanation:
which of the following correctly describes osmosis? choose one: a. the movement of water from an area of high solute concentration to an area of low solute concentration b. the movement of water from an area of low solvent concentration to an area of high solvent concentration c. the movement of water from an area of low solute concentration to an area of high solute concentration d. the movement of water from an area of low water concentration to an area of high water concentration
The correct answer is c. Osmosis is the movement of water from an area of low solute concentration to an area of high solute concentration.
This movement occurs across a semi-permeable membrane that allows water molecules to pass through, but not solute molecules.
In osmosis, the movement of water occurs until equilibrium is reached, where the concentration of solutes on both sides of the membrane is equal. This process is important in living organisms, as it allows for the regulation of water and solute balance in cells and tissues.
Option a is incorrect, as the movement of water is towards an area of high solute concentration, not low solute concentration.
Option b is incorrect, as osmosis refers specifically to the movement of water, not solvent in general.
Option d is incorrect, as the movement of water is towards an area of low solute concentration, not low water concentration.
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You want to make 100mL of a 0.1M KCl solution. How many grams of KCl are needed? Note that the compound consists of potassium and chlorine, not potassium, carbon and iodine.
1). 74.5g
2). 7.45g
3). 0.745g
4). 0.0745g
According to molar concentration, 0.7455 g of KCl are needed to make 0.1 M KCl solution.
What is molar concentration?
Molar concentration is defined as a measure by which concentration of chemical substances present in a solution are determined. It is defined in particular reference to solute concentration in a solution . Most commonly used unit for molar concentration is moles/liter.
Molar concentration is calculated by the formula, molar concentration=mass/ molar mass ×1/volume of solution in liters.
In terms of moles, it's formula is given as molar concentration= number of moles /volume of solution in liters.
Substituting values in 1st formula mentioned,mass=molarity×molar mass×volume in liters=0.1×74.55×0.1=0.7455 g.
Thus,0.7455 g of KCl are needed to make 0.1 M KCl solution.
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The smallest unit that retains the properties of an element is aan)
atom
O molecule
proton
O compound
neutron
O electron
Answer:
Atom
Explanation:
An atom is the smallest unit which represents the an element.
It retains the chemical properties of an element.
What is the tonicity of the solution made of 0.3m glucose after the blood is added when the membrane is impermeable to glucose and permeable to water? glucose is a covalent molecule.
The tonicity of a solution refers to its ability to cause a change in the shape or size of cells by altering the water content.
In this case, since the membrane is impermeable to glucose but permeable to water, the glucose molecules cannot pass through the membrane, while water molecules can. Since the solution is made of 0.3M glucose, it means that the concentration of glucose in the solution is 0.3 moles per liter.
When blood is added, the impermeable membrane prevents glucose molecules from passing through, but water molecules can move freely. The presence of a higher concentration of glucose inside the membrane than in the blood creates a hypertonic environment. This causes water to move from the blood (where the concentration of solutes is lower) into the solution, via osmosis.
As a result, the solution will become more diluted as water enters it, causing it to expand and potentially change the shape or size of the cells.
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Which of these substances is basic in nature?
(1 Point)
Baking Soda
Curd
Lemon
Orange
Baking Soda is a substance is in nature.
Thus, An alkaline white powder called baking soda is a staple of contemporary kitchens. One significant brand is largely to blame for its rise. Dr. Austin Church and John Dwight, two brothers-in-law, joined forces to market baking soda in 1846 and baking soda.
The product was called Arm & Hammer Church & Co's bicarbonate of soda, and it was created in Dwight's kitchen. Arm & Hammer planned to demonstrate to the populace the ingredient's versatility by 1860.
They started handing out small cookbooks filled with recipes for various foods, including bread, cakes, cookies, puddings, and baking soda.
Thus, Baking Soda is a substance is in nature.
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What does the release or absorption of energy indicate
Answer:
Chemical Change
Explanation:
What common error in handling a microscope can account for pipetting too much reagent into a tube? What errors account for under-pipetting?
The common error in handling a microscope that can account for pipetting too much reagent into a tube is not properly focusing the microscope, and the errors accounting for under-pipetting are improper pipette calibration, not holding the pipette vertically, or not fully releasing the pipette plunger when dispensing the reagent.
Not properly focusing or adjusting the microscope before viewing the sample can lead to an incorrect estimation of the sample volume needed, causing you to add more reagent than necessary.
To avoid over-pipetting:
Ensure that the microscope is properly adjusted and focused on the sample.
Double-check the required reagent volume before pipetting.
Use a pipette with the appropriate volume range for better accuracy.
The errors that can account for under-pipetting include not properly calibrating the pipette or not using the correct pipette volume for the desired amount of reagent. These can lead to an insufficient amount of reagent being added to the sample. Additionally, not properly mixing or shaking the reagent before pipetting can result in uneven distribution of the reagent and inaccurate pipetting.
To avoid under-pipetting:
Calibrate your pipette regularly to ensure accurate measurements.
Hold the pipette vertically while pipetting to avoid any angle-related discrepancies.
Ensure the pipette plunger is fully released when dispensing the reagent.
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me of an Irregular Solid
Use the image to determine the volume of the rock.
Initial volume:
mL
Final volume:
Volume of rock: 20
mL
cm³
The volume of the irregular solid from the image that have been shown is 12 mL
How do you determine the volume of an irregular solid?To obtain the volume of the irregular solid;
a. Measure the initial volume of water in the cylinder.
b. Carefully lower the irregular solid into the water, ensuring it is fully submerged without trapping any air bubbles.
c. Record the new volume of water in the cylinder.
d. The volume of the irregular solid is equal to the difference between the final and initial water volumes.
The volume is;
32 mL - 20 mL = 12 mL
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An experiment was conducted to determine if the intermolecular forces in two liquids affects their boiling points. Each liquid was sprayed on a paper towel. Each paper towel was wiped across a glass table to moisten the surface. The table shows a partial record of the experiment.
Given the partial record of the experiment, the information that should be recorded in the last column of the table is B. Time is taken by the glass surface to dry.
What is an intermolecular force?These are forces of attraction between atoms, molecules, and ions when they are placed close to each other.
Intermolecular forces are electrostatic in nature, and this means that they arise from the interaction between positively and negatively charged species.
Hence, an intermolecular force acts between molecules and their examples are London dispersion forces, dipole-dipole interaction, ion-dipole interaction, and van der Waals forces.
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The complete question
An experiment was conducted to determine if the intermolecular forces in two liquids affect their boiling points. Each liquid was sprayed on a paper towel. Each paper towel was wiped across a glass table to moisten the surface. The table shows a partial record of the experiment.
Experimental Record
Liquid Intermolecular Forces ?
А relatively strong
B relatively weak
What information should be recorded in the last column of the table?
Time is taken by the liquids to start boiling
Time is taken by the glass surface to dry
The volume of liquid required to moisten the paper towels
Time taken by the paper towels to become completely moist
Which model best represents the modifications to
the theory that Thomson's results made
necessary?
Answer:A
Explanation:
please answer this question correctly
cholesterol is synthesized in the liver from building blocks of
Answer:
Cholesterol is synthesized in the liver from building blocks of acetyl-CoA and acetoacetyl-CoA.Cholesterol is a kind of lipid that is made by the liver in all animals, including humans.
Explanation:
It's a crucial building block for cell membranes and hormones. When there's too much cholesterol in the blood, it can collect in the arteries and cause them to narrow, raising the risk of heart disease and stroke.
Acetyl-CoA and acetoacetyl-CoA are the building blocks of cholesterol. Acetyl-CoA is made from glucose during glycolysis and the citric acid cycle, which occurs in the mitochondria of cells.
Acetyl-CoA is used to make a variety of molecules, including cholesterol and fatty acids.Acetyl-CoA is converted to HMG-CoA in the liver, which is then converted to mevalonate. Cholesterol is made by mevalonate. So, acetyl-CoA and acetoacetyl-CoA are the building blocks of cholesterol.
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Is mixing salt and pepper physical change or chemical change ?
Answer:Cutting, tearing, shattering, grinding, and mixing are further types of physical changes because they change the form but not the composition of a material. For example, mixing salt and pepper creates a new substance without changing the chemical makeup of either component.
Explanation:
How long does cream of tartar activate
If moving objects have kinetic energy, do moving atoms kinetic energy?
Answer:
yes, if they were in rest they would have potential energy
Explanation:
A battery contains two metals that have different tendencies to attract electrons. If one is lithium with an electron affinity of −3.05, and the other is zinc with an electron affinity of −0.76, describe how the electrons will flow. Then, describe how you could make this an even stronger battery.
This battery could be made stronger when we make lithium the anode and make zinc the cathode.
What is the electron affinity?We know that the term electron affinity has to do with the fact the a specie is able to attract electrons. Hence, the specie that can be able to attract electrons is said to be have a greater electron affinity.
If we look at the order of the reactivity of the metals, we can see that the lithium has more tendency to exist as a positive ion as such the electron affinity of the lithium atom is very negative and it does not attract electrons.
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the yeastengages in photosynthesis, which produces oxygen gas, bio, quizletquizlet
The statement “the yeast engages in photosynthesis, which produces oxygen gas” is incorrect. Yeast cells do not engage in photosynthesis to produce oxygen gas.
What is photosynthesis?Photosynthesis is the process by which green plants use sunlight, carbon dioxide, and water to produce glucose (a simple sugar), which serves as food for the plant.
Oxygen is also produced during photosynthesis.Yeast:Yeast is a unicellular fungus that converts sugar into carbon dioxide and alcohol. Yeast cells respire aerobically in the presence of oxygen and anaerobically in the absence of oxygen.
However, yeast cells do not perform photosynthesis. They do not have chloroplasts or pigments that are required for photosynthesis. Therefore, yeast cells cannot produce oxygen gas.Bio quizlet:Quizlet is an online learning platform that allows users to create and share flashcards, study guides, and quizzes.
It is a great resource for studying biology and other subjects. Students can create their own study materials or use existing ones created by other users. Quizlet provides an engaging and interactive way to learn and retain information.
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An increase in the biodiversity of an ecosystem leads to an increase in its productivity.
The increase in the diversity of species in an ecosystem definitely lead to an increase in the productivity from that ecosystem. Hence, the statement is true.
What is an ecosystem?An ecosystem is the regions in earth where a group of living things and their essential non living things reside. There are various kind of ecosystems such as aquatic systems, forests, deserts etc.
The biodiversity refers to the diverse species of plants , animals and all other kind of livings there. By raising the possibility that species would use complementary resources and by increasing the likelihood that a highly productive or efficient species is present in the population, increasing species diversity can impact ecosystem functions, such as production.
For instance, greater use of soil resources can boost ecosystem production when there is a large diversity of plants. Similarly, when diverse plants populate more dependent animal variants survives more.
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Answer:
A. True
Explanation:
Got it right on Edge 2023.
A block of aluminum occupies a volume of 15.0 mL and weighs 45 grams.