The rate constant of a first-order process that has an initial concentration of 0.5 M and a half-life of 116 s is 1.72 x 10⁻² s⁻¹.
What is the rate constant of a first-order process?In the context of chemical kinetics, the rate constant (k) is a proportionality factor that connects the reaction rate and the reactant concentration. It can be used to calculate the rate of a chemical reaction.
The following formula calculates the half-life of a first-order reaction:T1/2 = ln(2)/kSubstituting the values given, we get:116 = ln(2)/k
Hence, the value of the rate constant is k = ln(2)/116= 1.72 x 10⁻² s⁻¹.
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what happens when the first crystals of kno3 appear in the solution? what condition is achieved whenthe solid kno3 comes in contact with the dissolved ions in the saturated solution? show the equation.3. based on the gathered data, what happened to the temperatures when the crystals form as the totalvolume of solution increased? what does this trend indicate?
KNO3 is electrolyzed in an aqueous solution, and potassium is released at the cathode. KNO 3 in an aqueous solution electrolyzes, releasing potassium at the cathode.
The cathode releases K ions, whereas the anode releases NO 3. What is KNO3 (potassium nitrate)? Potassium nitrate is the scientific name for the substance KNO 3. Potassium nitrate, often known as saltpeter or nitre, is a white solid that dissolves in water and is created when potassium chloride and sodium nitrate solutions fractionally crystallize. In rocks in Brazil, South Africa, and electrolyzed, it occurs naturally as nitre. Materials: 10 mL graduated cylinder, KNO3, test tube, stir rod, weigh boats, hot plates, thermometer. Want assistance with a writing assignment.
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How do plants recycle hydrogen during cellular respiration?(1 point) Responses The hydrogen in water is recycled as glucose. The hydrogen in water is recycled as glucose. The hydrogen in glucose is recycled as hydrogen gas. The hydrogen in glucose is recycled as hydrogen gas. The hydrogen in glucose is recycled as water. The hydrogen in glucose is recycled as water. The hydrogen in hydrogen gas is recycled as glucose. The hydrogen in hydrogen gas is recycled as glucose.
Plants recycle hydrogen during cellular respiration, as the hydrogen in glucose is recycled as water. The correct option is d.
What is cellular respiration?Food molecules are broken down into energy, water, and carbon dioxide during cellular respiration. In the presence of oxygen, cells respire. Multiple chemical cycles are involved in cell respiration.
In plants, cellular respiration occurs but in a minimum amount, and in this process the hydrogen in combines with oxygen and forms water.
Therefore, the correct option is d. The hydrogen in glucose is recycled as hydrogen gas.
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Answer: Plants recycle hydrogen during cellular respiration, as the hydrogen in glucose is recycled as water. The correct option is d.
Explanation: What is cellular respiration?
Food molecules are broken down into energy, water, and carbon dioxide during cellular respiration. In the presence of oxygen, cells respire. Multiple chemical cycles are involved in cell respiration.
In plants, cellular respiration occurs but in a minimum amount, and in this process the hydrogen in combines with oxygen and forms water.
Therefore, the correct option is d. The hydrogen in glucose is recycled as hydrogen gas.
help meeeeeeeee pleaseeeeeeeeeee
what mass of potassium sulfate is needed to make 2500.0ml of 2.0m solution?
(ANSWER THIS AND SHOW THE WORRRKKKKK, AND EXPLAINNN IT) THIS ISSS 60 POIUNTS PLZZ TAKE IT SERIOSLY
Molarity
Chemists primarily need the concentration of solutions to be expressed in a way that accounts for the number of particles that react according to a particular chemical equation. Since percentage measurements are based on either mass or volume, they are generally not useful for chemical reactions. A concentration unit based on moles is preferable. The molarity (M) of a solution is the number of moles of solute dissolved in one liter of solution. To calculate the molarity of a solution, you divide the moles of solute by the volume of the solution expressed in liters.
Note that the volume is in liters of solution and not liters of solvent. When a molarity is reported, the unit is the symbol M and is read as “molar”. For example a solution labeled as 1.5 M NH 3 is read as “1.5 molar ammonia solution”.
Sample Problem: Calculating Molarity
A solution is prepared by dissolving 42.23 g of NH 4 Cl into enough water to make 500.0 mL of solution. Calculate its molarity.
Step 1: List the known quantities and plan the problem.
& underline{text{Known}} &&underline{text{Unknown}} \& text{mass}=42.23 text{g} NH_4Cl && text{molarity}= ? text{ M}\& text{molar mass} NH_4Cl=53.50 text{g} / text{mol} \& text{volume solution}=500.0 text{mL}=0.5000 text{L}
The mass of the ammonium chloride is first converted to moles. Then the molarity is calculated by dividing by liters. Note the given volume has been converted to liters.
Step 2: Solve.
42.23 text{ g } NH_4Cl times frac{1 text{ mol } NH_4Cl}{53.50 text{ g } NH_4Cl} &= 0.7893 text{ mol } NH_4Cl\frac{0.7893 text{ mol } NH_4Cl}{0.5000 text{ L}} &= 1.579 text{ M}
Step 3: Think about your result.
The molarity is 1.579 M, meaning that a liter of the solution would contain 1.579 mol NH 4 Cl. Four significant figures are appropriate.
In a laboratory situation, a chemist must frequently prepare a given volume of solutions of a known molarity. The task is to calculate the mass of the solute that is necessary. The molarity equation can be rearranged to solve for moles, which can then be converted to grams. See sample problem 16.3.
Sample Problem:
A chemist needs to prepare 3.00 L of a 0.250 M solution of potassium permanganate (KMnO 4 ). What mass of KMnO 4 does she need to make the solution?
Step 1: List the known quantities and plan the problem.
Known
molarity = 0.250 M
volume = 3.00 L
molar mass KMnO 4 = 158.04 g/mol
Unknown
mass KMnO 4 = ? g
Moles of solute is calculated by multiplying molarity by liters. Then, moles is converted to grams.
Step 2: Solve.
text{mol KMnO}_4 = 0.250 text{ M KMnO}_4 times 3.00 text{ L} &= 0.750 text{ mol KMnO}_4\0.750 text{ mol KMnO}_4 times frac{158.04 text{ g KMnO}_4}{1 text{ mol KMnO}_4} &=119 text{ g KMnO}_4
Step 3: Think about your result.
When 119 g of potassium permanganate is dissolved into water to make 3.00 L of solution, the molarity is 0.250 M.
03:58:40
If the kinetic and potential energy in a system are equal, then the potential energy increases. What happens as a result?
Total energy increases.
Stored energy decreases.
Energy of motion decreases.
Total energy decreases.
Answer:
If the kinetic and potential energy in a system are equal, then the potential energy increases. What happens as a result? Total energy increases.
Answer:
its C energy of motion decreases
Explanation:
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Convert 7g/dm^3 of H2O to mol/dm^3
Conversion of 7g/dm³ of H₂O to 0.21 mol/dm³ is
Conversion is the act or process of changing something into a different state or form
Here given data is
7g/dm³ of H₂O we have to convert it into mol/dm³ = ?
Then divide by the relative formula mass
We get H₂O then H = 1 here 2 hydrogen = 1×2 = 2 and 1 oxygen i.e 1×16 = 16 =
2×16 = 32
So, 7g/dm³/32
= 0.21 mol/dm³
7g/dm³ of H₂O to 0.21 mol/dm³
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a physiciist is studying the nature of static discharge by appying a volatge across a microscopic tube filled with nitrogen
The process that correctly describes the growth in the number of ionized nitrogen molecules over time is D. The number of ionized molecules increases exponentially with each ionized molecule ionizing 3 other molecules every nanosecond.
Let's analyze the equation tN2 = 3⋅N, where N is the number of ionized molecules and t is the time in nanoseconds.
The equation states that the number of ionized molecules at time t is equal to 3 times the number of ionized molecules at the previous time step.
This implies that each ionized molecule ionizes 3 other molecules every nanosecond.
A physicist is studying the nature of static discharge by applying a voltage across a microscopic tube filled with nitrogen.
Static discharge is an event that takes place when there is a sudden flow of electric charge between two objects with different electrical potentials. This electric charge transfer results in a brief burst of electromagnetic energy (EMI or EMF), which can sometimes be observed as a visible spark in low-light conditions or heard as a crackling sound in high-quality audio systems.
The nature of static discharge is dependent on a variety of factors, including the composition of the material, the temperature and humidity, the electrical potential between the two objects, and the distance between the objects. Typically, static discharge occurs more frequently in environments with low humidity, such as during the winter months or in arid regions, as moisture acts as an insulator and prevents the buildup of electrical charge. In addition, materials that are good electrical conductors, such as metals, are more likely to experience static discharge than materials that are poor conductors, such as plastics or rubber.
Therefore, the correct description of the growth in the number of ionized nitrogen molecules over time is:
D. The number of ionized molecules increases exponentially with each ionized molecule ionizing 3 other molecules every nanosecond.
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Complete question is:
" physicist is studying the nature of static discharge by applying a voltage across amicroscopic tube filled with nitrogen molecules.Every nanosecond from then on, any ionized molecules willionize an additional number of molecules not already ionized, and ionization does not get lost.The equationtN2 3shows N, the number of ionized molecules, t nanoseconds after initiating a voltage.Which of thefollowing correctly describes the growth in the number of ionized nitrogen molecules over time?A.The number of ionized molecules increases linearly with each ionized molecule ionizing 2 other moleculesevery nanosecond.B.The number of ionized molecules increases linearly with each ionized molecule ionizing 3 other moleculesevery nanosecond.C.The number of ionized molecules increases exponentially with each ionized molecule ionizing 2 othermolecules every nanosecond.D.The number of ionized molecules increases exponentially with each ionized molecule ionizing 3 othermolecules every nanosecond."
Which Of The Following Species Has The Least Polar Bond? A. HCI B. HF C. HI D. HBr
Among the following species, HI has the least polar bond.
Polar covalent bond: The bond formed between two atoms having difference in electronegativity by sharing electrons.
Electronegativity is the tendency of an atom to attract electrons toward it and the trend of electronegativity in the modern periodic table is it generally increases as you move from left to right across a period and decreases as you move down a group.
Now, compared to HF, HCl, HBr, and HI the electrons shared between the atoms hydrogen and iodine are weak because iodine is a 5th-period element and has the least electronegativity hence the least polar bond between hydrogen and iodine molecule.
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2 Al + 3S ---> Al2S3
If 5.53g of Al2S3 are produced, how many grams of S would be used?
Mass of sulfur is 3.45g. Mole, often abbreviated as mol, is a commonly used unit of measurement in chemistry.
What is mole?Mole, often abbreviated as mol, is a commonly used unit of measurement in chemistry for vast amounts of tiny objects like molecule, atoms, or other specific particles. In addition, starting on May 20, 2019, the General Conference on Measures and Weights declared the mole as the quantity of the International System of Units. Additionally, practically all compounds have the same amount of additional particles or atoms in a mole.
2 Al + 3S \(\rightarrow\) Al\(_2\)S\(_3\)
moles of Al\(_2\)S\(_3\)=5.53/150.16=0.036moles
The mole ratio between sulfur and Al\(_2\)S\(_3\) is 3:1
moles of sulfur= 3× 0.036=0.108moles
mass of sulfur= 0.108×32=3.45g
Therefore, mass of sulfur is 3.45g.
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If 18 grams of Ca combines with 22 grams of S to form a compound with a
mass of 40 grams, what will be the percent composition of S in the
compound?
The per cent composition of S in the compound can be found by the following formula:% composition of S in the compound = (mass of S in the compound / total mass of the compound) × 100.
We are given the mass of the compound, which is 40 grams, but we need to find the mass of S in the compound. To find the mass of S in the compound, we can subtract the mass of Ca from the total mass of the compound: Mass of S in the compound = Total mass of the compound - Mass of Ca in the compound. Mass of S in the compound = 40 g - 18 g, Mass of S in the compound = 22 g.
Now, we can substitute the values we have into the per cent composition formula:% composition of S in the compound = (22 g / 40 g) × 100% composition of S in the compound = 55%.
Therefore, the per cent composition of S in the compound is 55%.
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What is believed to happen at absolute zero?
Mr. Stark thinks that a special juice will increase the productivity of workers. He creates two groups of 50 workers each and assigns each group the same task (in this case, they're supposed to staple a set of papers). Group A is given the special juice to drink while they work. Group B is not given the special juice. After an hour, Mr. Stark counts how many stacks of papers each group has made. Group A made 1,587 stacks, Group B made 2,113 stacks.
Identify the independent variable and dependent variable
Identify the control group and experimental group
Explanation:
taking a special juice independent variable
the number of stuck of paper dependent variable
the control group is group B
experimental group is Group A
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calculate the molar concentration of the solution formed when 8g of sodiumhydroxide is dissolved in 1dm³of water
Answer:
wow I can't believe you. your cheating I'm giving you a f on this. unless you tell me in front of the class that you cheated. I'm joking man but seriously I don't know
certain reaction has an activation energy of 34.34 kj/mol. 34.34 kj / mol. at what kelvin temperature will the reaction proceed 3.00 3.00 times faster than it did at 357 k?
Certain reaction has an activation energy of 34.34 kj/mol. At 428.0 kelvin temperature will the reaction proceed 3.00 3.00 times faster than it did at 357 k?
The physical concept of temperature indicates in numerical form how hot or cold something is. A thermometer is used to determine temperature. Thermometers are calibrated using a variety of temperature scales, which historically defined distinct reference points and thermometric substances. The most popular scales are the Celsius scale, sometimes known as centigrade, with the unit symbol °C, the Fahrenheit scale (°F), and the Kelvin scale (K), with the latter being mostly used for scientific purposes. One of the International System of Units' (SI) seven base units is the kelvin.
k1/k2 = \(e^{((Ea/R) * ((1/T2) - (1/T1)}\)
Ea = 34.34 kJ/mol × 1000 J/kJ
= 34,340 J/mol
3.00 = \(e^{((34,340 J/mol / (8.314 J/mol K)) × ((1/T2) - (1/357 K)))}\)
ln(3.00) = (34,340 J/mol / (8.314 J/mol K))×((1/T2) - (1/357 K))
T2 = 1 / (ln(3.00) / (34,340 J/mol / (8.314 J/mol K)) + (1/357 K)) = 428.0 K
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If you roll a bowling ball and a marble at the same
speed, which one has more Kinetic Energy?
Answer:
The marble
Explanation:
Even though they both have kinetic energy, the marble has more since the weight of the bowling ball is heavier, leaving it to stop faster than the marble itself.
Which is more reliable to measure accurate volume?
A) Test tube
B) Beaker
C) Measuring cylinder
D) Pipette
Answer:
Measuring cylinder
Explanation:
test tube/beaker don't usually have numbers, and a pipette is usually too small so a measuring cylinder will be the most accurate
In comparing groups, the first or the second, which group was more precise or was the precision the same
Comparing the data obtained online, the first group is more precise
The reason the above selection is correct is as follows;
Question: Parts of the question appear missing from a similar question online and included here;
First Group:
\(\begin{array}{|c|c|c|c|c|c|c|} Team \ a &Team \ b&Team \ c&Team \ d&Team \ e&Team \ f&Team \ g\\2.77 \ cm&2.60 \ cm&2.80 \ cm&2.65 \ cm&2.75 \ cm&2.65 \ cm& 2.68 \ cm\end{array}\right]\)
Second Group
\(\begin{array}{|c|c|c|c|c|c|c|} Team \ a &Team \ b&Team \ c&Team \ d&Team \ e&Team \ f&Team \ g\\2.70 \ cm&2.78 \ cm&2.62 \ cm&2.65 \ cm&2.75 \ cm&2.80 \ cm& 2.60 \ cm\end{array}\right]\)
Calculations for the first group:
The average = (2.77 + 2.60 + 2.80 + 2.65 + 2.75 + 2.65 + 2.68)/7 = 2.7
The range = 2.80 - 2.60 = 0.20
The approximate ± range of the average = ±0.2/2 = ±0.1
The precision of the first measurement is 2.7 ± 0.1 cm
Calculations for the second group:
The average = (2.70 + 2.78 + 2.62 + 2.65 + 2.75 + 2.80 + 2.60)/7 = 2.7
The range = 2.80 - 2.60 = 0.20
The approximate ± range from the average = ±0.2/2 = ±0.1
The range of values from the average is approximately ±0.1 cm
The precision of the first measurement is 2.7 ± 0.1 cm
Method to determine precision:
Precision is given by the finding the average deviation and the standard deviation as follows;
\(\mathbf{Average \ deviation} = \dfrac{\sum \left | x - \mu \right |}{n}\)
\(\mathbf{Standard\ deviation} =\sqrt{\dfrac{\sum \left ( x - \mu \right )^2}{n}}\)
Where;
μ = The mean or average = 2.7
n = The number of items (count) of the data = 7
For the first group, we have;
\(\mathbf{\dfrac{\sum \left | x - \mu \right |}{n}} = \dfrac{0.07 + 0.1 + 0.1 + 0.05 + 0.05 + 0.05 + 0.02 }{7} = \mathbf{0.062857}\)
The average deviation of the first group = 0.062857
∑(x - μ)² ≈ 0.0328
\(\mathbf{The \ standard\ deviation} =\sqrt{\dfrac{0.0328}{7}} \approx \mathbf{0.068452}\)
For the second group, we have;
\(\mathbf{\dfrac{\sum \left | x - \mu \right |}{n}} = \dfrac{0.0+ 0.08 + 0.08 + 0.05 + 0.05 + 0.1 + 0.1 }{7} = \mathbf{0.06571428571}\)
∑(x - μ)² ≈ 0.0378
\(\mathbf{The \ standard\ deviation} =\sqrt{\dfrac{0.0378}{7}} \approx \mathbf{0.073485}\)
By using the average deviation, and standard deviation values, the deviation of the second group is more than the first group and therefore the first group is more precise
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In the following beta decay problem, C = ___________.
C = Ca
A = 20
B = 42
What happens in beta decay?₁₉⁴²K → ⁴²₂₀Ca + ⁰₋₁e
There is an addition of one electron. The atomic number increases by one.
Positrons or electrons make up beta particles (electrons with positive electric charge, or antielectrons). In a nucleus with an excessive number of protons or neutrons, beta decay happens when one of the protons or neutrons is converted into the other. A neutron degrades into a proton, electron, and antineutrino in beta minus decay. A proton degrades into a neutron, a positron, and a neutrino in beta plus decay.
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Salts can produce acidic, basic, or neutral solutions. Which salts produce acidic solutions?.
Depending on whether a salt contains the conjugate base of a weak acid as the anion (A), the conjugate acid of a weak base as the cation (BH+), or both, it can dissolve in water to create a neutral, basic, or acidic solution. Small, highly charged metal ions found in salts cause acidic solutions to form in water.
What is a salt ?
In chemistry, a compound called salt is created when an acid and a base react. The positive ion (cation) of a base and the negative ion (anion) of an acid make up a salt. A neutralizing reaction occurs when an acid and a base interact.
Salts are ionic substances in chemical language. Most people use the term "salt" to refer to sodium chloride, or table salt. Ionic bonds between sodium ions and chloride ions result in the formation of sodium chloride. The chemical formula is NaCl because there is one sodium cation (Na+) for every chloride anion (Cl-).
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Most chemical bonds are
Select one:
O a purely ionic.
stion
O b. purely covalent.
O c. partly ionic and partly covalent.
Od, metallic.
Answer:
partly ionic and partly covalent
what is geothermal energy ?
And how is it used?
geothermal energy, form of energy conversion in which heat energy from within Earth is captured and harnessed for cooking, bathing, space heating, electrical power generation, and other uses.
Answer:
it can use for you wanted to do and we can use it for our wants...
Explanation:
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BTS
The solubility of Z is 60 g/ 100 g water at 20 °C. How many grams of solution are produced when a saturated solution is prepared using 300 grams of water at the same temperature? a 240 b 180 c 120 d 480
Answer:
Saturated solution = 180 gram
Explanation:
Given:
Solubility of Z = 60 g / 100 g water
Given temperature = 20°C
Amount of water = 300 grams
Find:
Saturated solution
Computation:
Saturated solution = [Solubility of Z] × Amount of water
Saturated solution = [60 g / 100 g] × 300 grams
Saturated solution = [0.6] × 300 grams
Saturated solution = 180 gram
What is the most important reason for using hydrates in fire extinguishers?
-They keep fire extinguishers dry during shipping and storage.
-They make fire extinguishers more affordable for household use.
-They create foams that have high water content to help extinguish fires.
-They create high pressure in the cylinder to quickly force out the fire r*tardant.
The importance of the use of hydrates in fire extinguishers are;
-They keep fire extinguishers dry during shipping and storage.
-They create foams that have high water content to help extinguish fires.
They create high pressure in the cylinder to quickly force out the fire r*tardant.
What is a fire extinguisher?We know that a fire extinguisher has to do with any device that has been made in such a way that the device can be used to eliminate a flame that is burning. We all know that fore can be very destructive. This implies that it is important to be able to put out the fire so that it does not cause big problems.
The fire extinguisher is composed of certain chemical substances that are able to react together quickly and then be able to quench the flame of the reaction that is going on in the system.
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do our continents move? why? how?
Answer:
Yes, our continents are always slowly moving due to tectonic plates moving underneath the earths surface. :)
Explanation:
Answer:
by plate tectonics
Explanation:
plate tectonics is the process of earths place moving at a slow pace which is about only 1 to 2 cm a year
Write the expression for the equilibrium constant for each of the following reaction:
2Fe2O3(s)+3C(s)⇌4Fe(s)+3CO2(g)
A) Kc=[CO2]3
B) Kc=[Fe]4[CO2]3[Fe2O3]2[C]3
C) Kc=[Fe2O3]2[C]3[Fe]4[CO2]3
D) Kc=2[Fe2O3]3[C]4[Fe]3[CO2]
The correct expression for the equilibrium constant (Kc) for the reaction:
\(2Fe2O3(s) + 3C(s) ⇌ 4Fe(s) + 3CO2(g)\) is: \(Kc=[Fe]4[CO2]3/[Fe2O3]2[C]3\)
The equilibrium constant expression for the given reaction, \(2Fe2O3(s) + 3C(s) ⇌ 4Fe(s) + 3CO2(g)\) is written as the ratio of the product concentrations raised to their respective coefficients divided by the reactant concentrations raised to their respective coefficients.
The ratio of the equilibrium concentrations of the products to the concentrations of the reactants raised to their respective powers to match the coefficients in the equilibrium equation at equilibrium is K, according to the law of mass action. The equilibrium constant expression is known as the ratio, a condition where there is a balance between opposing and static forces.
In this case, it would be:
\(Kc = ([Fe]^4[CO2]^3)/([Fe2O3]^2[C]^3)\)
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The correct expression for the equilibrium constant for the given reaction is:
C) Kc=[Fe2O3]2[C]3[Fe]4[CO2]3
The equilibrium constant (Kc) for a chemical reaction is written using the concentrations of the species involved in the reaction. Here's the general format for writing the equilibrium constant expression:
For the generic reaction:
aA + bB ⇌ cC + dD
The equilibrium constant (Kc) expression would be: Kc = [C]^c [D]^d / [A]^a [B]^b
where [A], [B], [C], and [D] represent the concentrations of the respective species at equilibrium, and a, b, c, and d are the stoichiometric coefficients of the species in the balanced chemical equation.
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362.5
3. How many joules of heat are needed to raise the temperature of 15.0 grams of aluminum from 22.5°C
to 55.5°C, if the specific heat of aluminum is 9.0 x 10² J/kg°C?
4,455 joules of heat are needed to raise the temperature of 15.0 grams of aluminum from 22.5°C to 55.5°C.
How to calculate the amount of energy required to raise the temperature.First, we need to calculate the amount of energy required to raise the temperature of 15.0 grams of aluminum from 22.5°C to 55.5°C. We can use the following formula:
Q = m * c * ΔT
Where
Q is the amount of heat energy required m is the mass of the aluminumc is the specific heat capacity of aluminumΔT is the change in temperatureWe need to convert the mass of aluminum from grams to kilograms:
m = 15.0 g = 0.015 kg
Now we can substitute the values into the formula:
Q = (0.015 kg) * (9.0 x 10² J/kg°C) * (55.5°C - 22.5°C)
Q = (0.015 kg) * (9.0 x 10² J/kg°C) * (33°C)
Q = 4,455 J
Therefore, 4,455 joules of heat are needed to raise the temperature of 15.0 grams of aluminum from 22.5°C to 55.5°C.
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Help please!! I'll name you brainliest!!
Answer:
MgO
Explanation:
Which is an adequate description of the
compounds shown in the diagram?
н ннн
H-C-C-C-C-OH
! ! ! !
н ннн
н ннн
H-C-C-C-C-H
ĊĊ-
HH OHH
1.
They are isotopes of butanol.
2.
They are isomers of butanol.
3.
They are alkanes.
4.
They are alkenes.
Answer:
the correct answer to it will be
2. They are isomers of butanol
as In the first case the the position of the alcoholic group is in the 1st carbon atom of butane and in the second its located at the 2nd carbon atom of butane.
so the compound is same with same chemical formula but since the postion of alcoholic group is different in both they become each other's isomers.
13.Which shows the order of increasing ionization energy?
a.Si, Al, Mg, Na
b.Ga, Ge, As, Se
c.Be, Mg, Ca, Sr
d.F, Cl, Br, I
A 0.245-L flask contains 0.467 mol CO2 at 159
o
C. Calculate the pressure: (a) Using the ideal gas law (b) Using the van der Waals equation (c) Explain the reason for the difference. (d) Identify which correction (that for P or V) is dominant and why.
(a) Using the ideal gas law, the pressure in the flask is approximately 11.43 atm.
(b) Using the van der Waals equation, the pressure in the flask is approximately 9.44 atm.
(c) There is a difference between the pressures because the van der Waals equation accounts for the volume of the molecules and the attractive and repulsive forces between them.
(d) The correction for the volume of the molecules is more significant than the correction for the attractive forces between molecules because the volume correction is proportional to the amount of gas. Since the amount of gas is relatively small compared to the square of the amount of gas, the correction for the volume of the molecules is more significant.
a) The ideal gas law is PV = nRT. Here, P is the pressure, V is the volume, n is the number of moles of gas, R is the gas constant, and T is the temperature.
Using the ideal gas law:
PV = nRTP = (nRT)/V
Where,
P = Pressure of CO₂
n = Number of moles of CO₂
V = Volume of CO₂
T = Temperature of CO₂
R = Gas constant = 0.08206 L-atm/mol-K (This value can be converted to other units based on the unit of pressure, volume, and temperature used in the problem)
Substitute the values into the formula:
P = (0.467 mol * 0.08206 L-atm/mol-K * (159°C + 273.15)) / 0.245 L
P = 11.43 atm (approximately)
b) The van der Waals equation is given as (P + an²/V²)(V - nb) = nRT, where a and b are constants based on the properties of the gas being used. Since CO₂ is a gas composed of polar molecules, the van der Waals constant, "a," is nonzero, while the van der Waals constant, "b," accounts for the size of the gas molecules and is also nonzero for CO₂.
Using the van der Waals equation:
(P + an²/V²)(V - nb) = nRT
Solve for P. The value of a and b are 3.59 L²-atm/mol² and 0.0427 L/mol, respectively. Plug in the given values:
P = (nRT/(V - nb)) - (an²/V²)(a)
P = ((0.467 mol * 0.08206 L-atm/mol-K * (159°C + 273.15 K))/(0.245 L - (0.0427 L/mol * 0.467 mol))) - ((3.59 L²-atm/mol² * 0.467 mol²)/(0.245 L)²)(b)
P = 9.44 atm (approximately)
c) The van der Waals equation is an improvement over the ideal gas law because it accounts for the volume of the molecules and the attractive and repulsive forces between them that become significant at high pressures and low temperatures. At low pressures and high temperatures, the ideal gas law works well since the forces between molecules are negligible and the volume of the molecules is relatively small. However, at high pressures and low temperatures, the volume of the molecules and the attractive forces between them become significant, resulting in the deviation of gases from ideal behavior.
d) In this case, the correction for the volume of the molecules (represented by "b") is more significant than the correction for the attractive forces between molecules (represented by "a"). This is because the volume correction is proportional to the amount of gas, while the correction for the attractive forces is proportional to the square of the amount of gas. Since the amount of gas is relatively small compared to the square of the amount of gas, the correction for the volume of the molecules is more significant.
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