The structural formula of the principal organic product formed when benzonitrile is treated with CH3MgBr followed by work-up with dilute acid: C6H5-C(=NH)-CH3
To draw the structural formula of the principal organic product formed when benzonitrile is treated with CH3MgBr followed by work-up with dilute acid, follow these steps:
1. Start with the structure of benzonitrile, which has a benzene ring attached to a cyano group (C≡N).
2. Identify the nucleophile and electrophile in the reaction. CH3MgBr is a Grignard reagent, and the CH3- is a nucleophile. In benzonitrile, the electrophilic carbon is the one in the cyano group.
3. The nucleophilic CH3- attacks the electrophilic carbon in the cyano group, breaking the triple bond and forming a new bond between the carbon atoms.
4. The intermediate formed now has a negative charge on the nitrogen atom.
5. In the next step, the intermediate is treated with dilute acid. The negatively charged nitrogen atom captures a proton (H+) from the acid, neutralizing the charge and forming an imine.
6. The final product is N-methylbenzaldimine, which has a benzene ring attached to an imine group with a methyl group bonded to the nitrogen atom.
The structural formula of the principal organic product is:
C6H5-C(=NH)-CH3
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If H 2
and Cl 2
are mixed, how will they interact based on your knowledge of chemical bonds?
The reaction of the hydrogen and the chlorine atoms would lead to the formation of HCl
Formation of HClIn this reaction, each chlorine molecule (Cl2) breaks apart into two chlorine atoms (Cl), and each hydrogen molecule (H2) breaks apart into two hydrogen atoms (H). These reactive atoms then combine to form hydrogen chloride molecules (HCl).
It's worth noting that the reaction between hydrogen gas and chlorine gas is highly exothermic and releases a significant amount of energy.
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why is OH on the outside of the lewis structure for methanol?
In the Lewis structure of methanol (CH3OH), the OH group is placed on the outside because it is an important functional group that influences the chemical properties and reactivity of the molecule.
The Lewis structure is a representation of a molecule that shows the arrangement of atoms and valence electrons. In methanol, carbon (C) is the central atom bonded to three hydrogen (H) atoms and one oxygen (O) atom. The oxygen atom forms a single bond with carbon and also has two lone pairs of electrons.
The placement of the OH group (hydroxyl group) on the outside of the Lewis structure is significant because it determines the chemical behavior of methanol. The OH group consists of an oxygen atom bonded to a hydrogen atom and represents the presence of an alcohol functional group.
In organic chemistry, functional groups are specific arrangements of atoms within a molecule that give rise to characteristic chemical reactions and properties. The presence and position of functional groups can greatly influence the behavior and reactivity of a compound. In the case of methanol, the hydroxyl group provides the molecule with its characteristic properties.
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what do you predict for the height of a barometer column based on 1-iodododecane, when the atmospheric pressure is 752 torr ?
8.52 m is the height of a barometer column based on 1-iodododecane.
What is a barometer?A barometer is described as a scientific instrument that is used to measure air pressure in a certain environment.
For the given question we will use the below formula:
P = dgh, where
g = gravitational force = 9.8 m/s²
h = height
First we calculate the height of the barometer column for the mercury:
Density of mercury = 13.6g/ml (given)
Given pressure = 752 torr =100258.144 N/m²
Height of barometer for mercury = 100258.144 / (13.6×9.8) = 752.23= 0.752
Now we calculate the height of barometer by using the below formula:
d₁h₁ = d₂h₂, where
d₁ = density of 1-iodododecane = 1.20g/mol (given)
h₁ = to find?
d₂, h₂ = density & height with respect to mercury
On putting all values in the above equation we get,
h₁ = 13.6×0.752 / 1.20 = 8.52m
Hence, 8.52m is the height of barometer.
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Complete question:
The compound 1-iodododecane is a nonvolatile liquid with a density of 1.20g/ml. the density of mercury is 13.6g/ml. part a what do you predict for the height of a barometer column based on 1-iodododecane, when the atmospheric pressure is 752 torr ?
The element iodine appears in
Period 5 of the Periodic Table. This
means that an iodine atom has-
A five electrons in its outer orbital
B five orbitals in its electron cloud
C an atomic mass greater than four
D five protons and five neutrons in its nucleus
The element iodine appears in Period 5 of the Periodic Table. This means that an iodine atom has five orbitals in its electron cloud. so the correct option is (b).
As a member of group 7, iodine possesses seven outer electrons. Since it is in the fifth period, its electrons will be in orbitals 5s and 5p. The chemical formula for iodine is 5s25px25py25pz1.
What does iodine's orbital notation mean?total amount of electrons that could occupy each orbital
Again using iodine as an example, we can observe on the periodic table that it has an atomic number of 53. ( In neutral state it contains 53 electrons). The configuration of the entire electron cloud is 1s22s22p63s23p64s23d104p65s24d105p5.
Facts about Iodine:Iodine is a trace element that can be found as a dietary supplement, as well as naturally in some foods and some forms of salt. Iodine is a necessary component of the thyroid hormones triiodothyronine (T3) and thyroxine (T4) (T3).
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Atoms of hydrogen can become helium atoms during a chemical reaction.
True
False
Answer:
false
in chemical reaction element doesnot change into another
Explanation:
How many of the following are buffered solutions? Explain.
A weak acid as well as its corresponding base make up a buffered solution. The ions are represented by violet, grey, and green spheres, respectively. The first system represents the buffer.
What is buffer?A buffer is indeed a solution that resists pH fluctuations and contains either one weak acid as well as its salt or even a weak base as well as its salt. To put it another way, a buffer is indeed an aqueous solution that includes a weak base as well as its conjugate acid, or a weak acid as well as its conjugate base.
A buffer may also be referred to as a buffer solution, hydrogen ion buffer, and pH buffer. A weak acid as well as its corresponding base make up a buffered solution. The ions are represented by violet, grey, and green spheres, respectively. The first system represents the buffer.
Therefore, the first system represents the buffer.
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(2S,3R)-2-Bromo-3-phenylbutane undergoes an E2 elimination when treated with sodium ethoxide. Draw all possible Newman projections for the bond relevant for the elimination reaction, and use those Newman projections to explain the stereochemical outcome of the reaction. Draw the final product and provide its IUPAC name.
Answer: (2S,3S)-2-Bromo-3-phenylbutane will undergo E2 reaction and form trans product of elimination due to its thermodynamic stability
Explanation:
A farmer wants to start growing sweetcorn on his farm. He has found out that sweetcorn grows best in soil with a pH value of approximately 7.5. Explain how he can use the knowledge of acids, alkalis, and neutralisation to find out the pH value of his soil to make sure he gets the best crop possible
Answer:
The process to use this knowledge is explained as below:
Explanation:
1. Farmer should use an indicator to check the pH value of the soil of the field of the farm.
2. If the field or the farm has alkali soil add acid to reduce the pH value.
3. If the soil of the farm is acidic for the crop add alkali to increase the pH value.
4. It will be a neutralization reaction and changes the pH value of the farm.
5. Weather/leeching into the surrounding soil/plant or animal waste will lead to a change in pH value over time.
6. The pH value will need to be regularly monitored and adjusted.
PLEASEEE HELP ME
Sulfuric acid is the most produced industrial chemical in the world. The chemical process involves many steps – the final step combines oleum (H2S2O7) with water to produce sulfuric acid (H2SO4). For the first batch of acid production, 1.20 kilograms of oleum is reacted with excess water, and 435 grams of sulfuric acid are produced.
• Write the balanced equation for the formation of sulfuric acid from oleum and water.
• Calculate the theoretical yield of sulfuric acid. Work must be shown to earn credit.
• Calculate the percent yield for the sulfuric acid production. Work must be shown to earn credit
Answer:
Balanced equation: H₂S₂O₇ + H₂O → 2H₂SO₄
Theoretical yield of H₂SO₄: 1322 g
Percent yield for the H₂SO₄ production: 33%
Explanation:
First of all, we determine the balanced equation:
H₂S₂O₇ + H₂O → 2H₂SO₄
Stoichiometry says that 1 mol of oleum reacts to 1 mol of water in order to produce 2 moles of sulfuric acid.
1.20 kg = 1200 g
We convert the grams to moles → 1200 g . 1mol/ 178.12g = 6.74 mol
Ratio is 1:2, so if we have 6.74 mol of oleum we can produce the double of moles of acid. (6.74 . 2) = 13.48 moles of acid.
This is the 100 % yield reaction, or it can be called theoretical yield.
We convert the moles to mass → 13.48 mol . 98g /1mol = 1322 g of acid may be produced.
In the problem, they said we produced 435 g of acid, so let's determine the percent yield.
Percent yield of reaction = (Produced yield / Theoretical yield) . 100
Percent yield of reaction = (435 / 1322) . 100 → 33 %
Someone help me please?
Suppose the interaction between two atoms by the Lennard-Jones potential: ULJ = B/r^12 - A / r^6 where the values of A and B are known to be A = 10^-77 J x m^6 and B = 10^-134 J x m^12.
What does the Lennard-Jones potential predict for the separation r=r eq
hen the energy is at the minimum (equilibrium) value, U min. What is the u min fot this interaction at T=298 K ? What is the ratio of U min to the purely attractive van der Waals component of the interaction potential at r eq.
What is the ratio of r eq to r 0 defined by u(r 0 )=0. 4. What is the ratio of r s to r 0 , where r s is the separation where the magnitude of the (attractive adhesion) force is maximum, F max . What is the value for F max between the two atoms?
a) The Lennard-Jones potential predicts the separation r_eq at the minimum energy U_min.
b) The U_min for this interaction at T=298 K is the value obtained from the Lennard-Jones potential equation when r=r_eq.
c) The ratio of U_min to the purely attractive van der Waals component of the interaction potential at r_eq can be calculated by comparing the attractive part (-A/r^6) to the total potential energy U_min.
d) The ratio of r_eq to r_0, where u(r_0)=0.4, can be determined by finding the value of r_eq where the potential energy is equal to 0.4 times the total potential energy at r=r_0.
e) The ratio of r_s to r_0, where r_s is the separation where the magnitude of the attractive adhesion force is maximum, can be determined by finding the value of r where the derivative of the potential energy with respect to r is equal to zero.
f) The value of F_max between the two atoms can be obtained by taking the negative derivative of the potential energy equation with respect to r and evaluating it at r=r_s.
a) The Lennard-Jones potential provides information about the relationship between energy and separation between two interacting atoms.
At the minimum energy (U_min), the potential predicts the separation r_eq, which corresponds to the equilibrium distance between the atoms. This is the distance at which the energy of the system is at its lowest point.
b) To determine the value of U_min at a given temperature (T=298 K), you can substitute the equilibrium separation r_eq into the Lennard-Jones potential equation and calculate the resulting energy value.
This will give you the U_min for the interaction.
c) The Lennard-Jones potential consists of two components: an attractive component (-A/r^6) and a repulsive component (B/r^12).
The ratio of U_min to the purely attractive van der Waals component of the interaction potential at r_eq can be calculated by comparing the magnitude of the attractive component to the total potential energy at the equilibrium separation.
This ratio provides insights into the relative contribution of the attractive force to the overall potential energy at equilibrium.
d) The ratio of r_eq to r_0 can be determined by finding the value of r_eq where the potential energy is equal to 0.4 times the total potential energy at r=r_0.
In other words, you need to solve the Lennard-Jones potential equation for r_eq when the potential energy is equal to 0.4 times the potential energy at r=r_0.
e) The ratio of r_s to r_0 is obtained by finding the value of r where the magnitude of the attractive adhesion force is maximum.
This can be determined by finding the separation r where the derivative of the potential energy equation with respect to r is equal to zero.
The value of r_s represents the separation at which the attractive force between the atoms is strongest.
f) The value of F_max between the two atoms can be obtained by taking the negative derivative of the Lennard-Jones potential energy equation with respect to r and evaluating it at r=r_s.
This will give you the magnitude of the maximum attractive adhesion force between the atoms.
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how many electrons does tellurium need to obtain the octet rule
Answer:
8
Explanation:
This number normally equals the number of electrons that atom needs to have a total of eight electrons (an octet) in its outer shell.
A boulder rests on a ledge 31.2 m above a lake. If it has 2.65 x 10 J of gravitational
potential energy relative to the lake surface, what is the mass of the boulder?
Answer:
This question is incomplete, the gravitational potential energy is 2.65 x 10^5 J
mass of the boulder = 866.7g
Explanation:
Potential energy (P.E) refers to the energy due to the position of a body. It can be calculated as follows:
P.E = m × g × h
Where;
m = mass of substance (g)
g = acceleration due to gravity (m/s²)
h = height (m)
According to the information provided in this question,
h = 31.2 m
g = 9.8m/s²
m = ?
P.E = 2.65 x 10^5 J
Using P.E = m × g × h
2.65 x 10^5 = m × 9.8 × 31.2
2.65 x 10^5 = 305.76m
265000 = 305.76m
m = 265000 ÷ 305.76
m = 866.69
mass of the boulder = 866.7g
5. Fill in the phase change diagram. Circle the ENDOTHERMIC processes.
3
Solid
Phase Change
Concept Map
Gas
Liquid
6
Answer:
1. Melting
2. Freezing
3. Sublimation
4. Deposition
5. Condensation
6. Evaporation
1, 3, 6 are endothermic processes
Baking soda, NaHCO3, decomposes when it is heated. How much heat will be absorbed by the decomposition of 5.25 moles of baking soda?
Answer:
The balanced reaction for the decomposition of baking soda is
2 NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(g)
We can find the heat of reaction by using the Hess' Law. This is done by using this formula:
∑(Hf,products) -∑(Hf,reactants) = Heat of reaction
where Hf is the heat of formation. According to literature, these are the heats of formation for each of the compounds in the reaction:
NaHCO3: -947.68 kJ/mol
Na2CO3: -1130.94 kJ/mol
CO2: -393.51 kJ/mol
H2O: -241.8 kJ/mol
Applying Hess' Law:
[1(-1130.94) + 1(-241.82)] + 1(-393.51)] - [2(-947.68)] = 129.09 kJ
Thus, the heat of reaction is 129.09 kJ/mol NaHCO3. Since there is 1.96 mol of NaHCO3, the total heat of reaction is 253.02 kJ
Explanation:
please mark me as brainlest
Explain why your hair sticks to a plastic (polyethylene) comb.
Answer:
Due to the accumulation of static charges/due to static electricity
Based on this equation, which of the following statements best describes what would be observed as the reaction takes place?
\(AgNO3(aq) + KCl(aq) ~~---\ \textgreater \ ~~ AgCl(s) + KNO3(aq)\)
a) silver chloride forming a solid precipitate (CORRECT)
b) solid silver dissolving
c) two clear solutions mixing to form one clear solution
d) bubbles forming from aqueous solution production
Answer:
a
Explanation:
i took the quiz
Write each chemical bond or elements of the chemical formula:2Mg + O2 -> 2MgO As a Lewis dot structure (while still in the formatting of the chemical formula).
1) Chemical formula
\(2Mg+O_2\rightarrow2MgO\)2) Mg Lewis structure
3) O2 Lewis structure
4) MgO Lewis structure
5) Chemical formula written as Lewis dot structure
.
True or false A recent investigation found relatively high levels of the metalloid
arsenic in samples of apple juice. This would not be harmful
because arsenic is a stable metalloid.
Answer:
False
Explanation:
I took the quiz and got it right
How many molecules are present in 3.6
moles CH₁?
Answer: There are 2.161 x 10^24 molecules present in 3.6 moles CH₁.
Explanation:
Molecules are the the lowest fundamental unit of a chemical molecule that can participate in a chemical reaction is a group of bound atoms. Avogadro's number is used to calculate the number of molecules present in a mole of a substance
Avogadro's number of particles, or around 6.022 x 1023 molecules, are present in one mole of any substance. Therefore the following would be present in 3.6 moles of CH1:
2.161 x 1024 particles are equal to 3.6 moles times 6.022 x 1023 particles per mole.
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In order for a substance to be considered a mineral, it must a. be a solid, liquid, or gas. b. be abundant in the crust. c. have atoms arranged in a random, non-repeating pattern. d. contain carbon.
Answer: i think its (b) be abundant in the crust
Explanation:
What is the name of this hydrocarbon? a skeletal model has 2 central carbons bonded to c h 3 at each end, and at the left of the 2 central carbons. 3-isopentane 2-methylbutane 3-methylbutane 1,2-methylpropane
The name of the given hydrocarbon in which 2 central carbon atoms with additional 3 methyl groups is 2-methylbutane.
What are hydrocarbons?Hydrocarbons are the organic compounds which are made up of by the combination of hydrogen and carbon atoms.
According to the question desired structure is attached below where:
2 and 3 number shows the central carbon atoms which are present in the hydrocarbon.1 and 4 number shows the methyl groups that are attached at each end.One extra methyl group is attach on the left side of 2nd central carbon atoms.Hence required hydrocarbon is 2-methyl butane.
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Answer:
B. 2-methylbutane
Explanation:
Correct on Edge 2022!!!
Good luck everyone, you got this! Have a great day!
Compound
a)magnesium+carbon+oxygen
b)copper+sultry+oxygen
c)barium+nitrogen+oxygen
a phase is a state of matter , such as a solid , a liquid or a gas
There is an insect that is so thin that it
is called a "walking stick." Locating this
insect requires a keen eye, for the
walking stick crawls along twigs and
easily blends in with the thin plant
branches.
This relationship of walking stick to plant
branch would best be classified as
Answer:
Explanation:
I think it’s mimetic. Correct me if I’m wrong.
If excess ammonium sulfate reacts with 20.0g of calcium hydroxide how many liters of ammonia are produced at STP?
(NH4) 2SO4 + Ca (OH) 2 --> CaSO4 + NH3 + H20
If excess ammonium sulfate reacts with 20.0g of calcium hydroxide then liters of ammonia are produced at STP 0.081L
Ammonium sulphate is the organic solvent and the primary use of ammonium sulphate is as a fertilizer for alkaline soils
Here given reaction is
(NH₄)₂SO₄ + Ca(OH)₂ → CaSO₄ + NH₃ + H₂O
Here given data is
Calcium hydroxide = 20.0g
We have to find liters of ammonia are produced at STP =?
20.0g of (NH₄)₂SO₄ STP = ?
Then 20.0g of (NH₄)₂SO₄×1 mol/132g×0.54L/1 mol = 0.081L
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3 Cu + 8HNO3 → 3 Cu(NO3)2 + 2 NO + 4 H2O
In the above equation, how many grams of water can be made when 15.9 moles of HNO3 are consumed?
Answer:
45673
Explanation:
Oxygen has a boiling point of 90.19k. What is the temprature in farenheit
Answer: −182.96 °C; −297.33 °F
I think
Answer:
162374 farenheit
Explanation:
You need to convert the 90.19k to Farenheit.
You can even use google, but if you need the formula it's (0°C × 9/5) + 32 = 32°F
A 0.245-L flask contains 0.467 mol CO2 at 159
o
C. Calculate the pressure: (a) Using the ideal gas law (b) Using the van der Waals equation (c) Explain the reason for the difference. (d) Identify which correction (that for P or V) is dominant and why.
(a) Using the ideal gas law, the pressure in the flask is approximately 11.43 atm.
(b) Using the van der Waals equation, the pressure in the flask is approximately 9.44 atm.
(c) There is a difference between the pressures because the van der Waals equation accounts for the volume of the molecules and the attractive and repulsive forces between them.
(d) The correction for the volume of the molecules is more significant than the correction for the attractive forces between molecules because the volume correction is proportional to the amount of gas. Since the amount of gas is relatively small compared to the square of the amount of gas, the correction for the volume of the molecules is more significant.
a) The ideal gas law is PV = nRT. Here, P is the pressure, V is the volume, n is the number of moles of gas, R is the gas constant, and T is the temperature.
Using the ideal gas law:
PV = nRTP = (nRT)/V
Where,
P = Pressure of CO₂
n = Number of moles of CO₂
V = Volume of CO₂
T = Temperature of CO₂
R = Gas constant = 0.08206 L-atm/mol-K (This value can be converted to other units based on the unit of pressure, volume, and temperature used in the problem)
Substitute the values into the formula:
P = (0.467 mol * 0.08206 L-atm/mol-K * (159°C + 273.15)) / 0.245 L
P = 11.43 atm (approximately)
b) The van der Waals equation is given as (P + an²/V²)(V - nb) = nRT, where a and b are constants based on the properties of the gas being used. Since CO₂ is a gas composed of polar molecules, the van der Waals constant, "a," is nonzero, while the van der Waals constant, "b," accounts for the size of the gas molecules and is also nonzero for CO₂.
Using the van der Waals equation:
(P + an²/V²)(V - nb) = nRT
Solve for P. The value of a and b are 3.59 L²-atm/mol² and 0.0427 L/mol, respectively. Plug in the given values:
P = (nRT/(V - nb)) - (an²/V²)(a)
P = ((0.467 mol * 0.08206 L-atm/mol-K * (159°C + 273.15 K))/(0.245 L - (0.0427 L/mol * 0.467 mol))) - ((3.59 L²-atm/mol² * 0.467 mol²)/(0.245 L)²)(b)
P = 9.44 atm (approximately)
c) The van der Waals equation is an improvement over the ideal gas law because it accounts for the volume of the molecules and the attractive and repulsive forces between them that become significant at high pressures and low temperatures. At low pressures and high temperatures, the ideal gas law works well since the forces between molecules are negligible and the volume of the molecules is relatively small. However, at high pressures and low temperatures, the volume of the molecules and the attractive forces between them become significant, resulting in the deviation of gases from ideal behavior.
d) In this case, the correction for the volume of the molecules (represented by "b") is more significant than the correction for the attractive forces between molecules (represented by "a"). This is because the volume correction is proportional to the amount of gas, while the correction for the attractive forces is proportional to the square of the amount of gas. Since the amount of gas is relatively small compared to the square of the amount of gas, the correction for the volume of the molecules is more significant.
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How many grams of NaCl, m.w. 58.5 daltons, are necessary to make 1 liter of 5% saline? A. 58.5 B.1 C. 6.02 X 10^23 0.2.9 E. 50
29.25 grams of NaCl, m.w. 58.5 daltons, are necessary to make 1 liter of 5% saline.
Molar concentration is a unit of measurement for the concentration of a chemical species, specifically a solute, in a solution, expressed as the amount of substance per unit volume of solution. The most often used unit for molarity in chemistry is the number of moles per litre, denoted by the unit symbol mol/L or mol/dm3 in SI units.
A solution's concentration is defined as the quantity of solute present in a given amount of solution. The concentration of any solution is defined as the solute divided by the volume of the solvent or solution. When represented as a percentage, it is known as mass by volume percent.
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