Given: 4.0 mL of methyl salicylate
a) Calculate the theoretical yield of salicylic acid from the given starting mass of methyl salicylate. Please also include the units from the calculations.
b) What key change do you expect to see in the IR spectrum when the ester starting material is converted to the carboxylic acid?
c) What key change do you expect to see in the 1H NMR spectrum when the ester starting material is converted to the carboxylic acid?

Answers

Answer 1

a)

To calculate the theoretical yield of salicylic acid from the given starting mass of methyl salicylate,

Explanation :

follow these steps:

1. Determine the molecular weights of methyl salicylate (C8H8O3) and salicylic acid (C7H6O3).

Methyl salicylate: 152.15 g/mol;

Salicylic acid: 138.12 g/mol

2. Calculate the mass of the 4.0 mL of methyl salicylate.

Assuming its density is 1.174 g/mL (check the actual density if available), mass = volume x density = 4.0 mL x 1.174 g/mL = 4.696 g.

3. Determine themoles of methyl salicylate:

moles = mass/mmolecular weight = 4.696 g/152.15 g/mol = 0.03083 mol.

4. Since the reaction between methyl salicylate and salicylic acid has a 1:1 stoichiometry, the moles of salicylic acid will be the same as the moles of methyl salicylate: 0.03083 mol.

5. Calculate the theoretical yield of salicylic acid: mass = moles x molecular weight = 0.03083 mol x 138.12 g/mol = 4.261 g.

The theoretical yield of salicylic acid from the given starting mass of methyl salicylate is 4.261 grams.



b)

In the IR spectrum, the key change when theester starting material (methyl salicylate) is converted to the carboxylic acid (salicylic acid) is the appearance of a broad O-H stretching band at around 2500–3300 cm1, indicating the presence of the carboxylic acid group.



c)

In the 1H NMR spectrum, the key change when the ester starting material (methyl salicylate) is converted to the carboxylic acid (salicylic acid) is the disappearance of the singlet peak corresponding to the methyl protons of the ester group (3.8 ppm) and the appearance of a new peak corresponding to the carboxylic acid proton (10–12 ppm).

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Related Questions

1.) what is the name of NaF formula

Answers

Answer:

\(\text{Sodium Fluoride}\)

Explanation:

Here, we want to get the name for the given chemical formula

Looking at the formula, we look at the names of the element

The names are sodium and fluorine

We write the name of the metal element first, then the non-metal atom

Thus, we have it as

\(\text{Sodium Fluoride}\)

What is the equilibrium constant for the reaction shown below?

glutathione + NADPH + H+ ↔ reduced glutathione + reduced glutathione + NADP+

A.
1.073

B.
1,487

C.
17.4

D.
0.073

E.
7.03

Answers

Kc = [GSH]2[NADP+]/[GSSG] [NADPH] [H+]= (2.47 × 10^-8)^2 (1.00 × 10^-5)/(3.59 × 10^-5)(1.00 × 10^-4) (1.00 × 10^-7)= 1.073. Hence, the answer is option A. 1.073.

The equilibrium constant for the reaction is given by the ratio of the product of the concentrations of the products raised to their stoichiometric coefficients to the product of the concentrations of the reactants raised to their stoichiometric coefficients.

However, the given reaction is as follows;glutathione + NADPH + H+ ↔ reduced glutathione + reduced glutathione + NADP+The corresponding equilibrium constant expression is,Kc = [GSH]2[NADP+]/[GSSG] [NADPH] [H+]Where;[GSH] = Concentration of glutathione[NADPH] = Concentration of NADPH[H+] = Concentration of hydrogen ions[GSSG] = Concentration of reduced glutathione.

On substitution,Kc = [GSH]2[NADP+]/[GSSG] [NADPH] [H+]= (2.47 × 10^-8)^2 (1.00 × 10^-5)/(3.59 × 10^-5)(1.00 × 10^-4) (1.00 × 10^-7)= 1.073Hence, the answer is option A. 1.073.

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What are the basic elements of selection of proffesion?describe any two​

Answers

Answer:

overall I think one answer

Which ion will combine with sulfide in a 2:1 ratio, and why?

a). chloride
b). magnesium ion
c). ammonium
d). nitrate

Answers

The ion which will combine with sulfide in a 2:1 ratio is Choice B: Ammonium.

The sulfide ion is negatively charged and needs two electrons to complete it's octet;

In essence, it needs two positive charges.

However, since the question asks Which ion will combine with sulfide in a 2:1 ratio.

The ion is ammonium ion; NH4+

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What is the molality of a solution made by dissolving 0.0816 moles of

C6H1206 into 150.0 g of water?

Answers

Answer:

m = 0.544 moles/kg

Explanation:

To do this, we need to use the expression for molality of a solution which is:

m = n / kg water

Where:

n: moles of solute

m: molality of solution

In this case, we have the moles of the solute, which is the C6H12O6 and the grams of water, and these grams would have to be turn into kg. Let's do this first:

kg of water = 150 g * 1 kg / 1000 g = 0.150 kg of water.

Now, replacing in the above expression of molality, we can calculate the molality of the solution:

m = 0.0816 / 0.150

m = 0.544 moles/kg

draw the dipeptide alanylvaline (ala−val) as it would exist at neutral ph. amino acid structures can be found in this table. include hydrogen atoms and all appropriate charges.

Answers

Ala-Val dipeptide at neutral pH: Ala is negatively charged (COO-), Val is positively charged (NH3+).

(Ala-Val) is a dipeptide composed of two amino acids: alanine (Ala) and valine (Val). At neutral pH, the carboxyl group (COOH) of alanine loses its hydrogen ion (H+) and becomes negatively charged (COO-), while the amino group (NH2) of valine gains a hydrogen ion (H+) and becomes positively charged (NH3+).

The dipeptide can be represented as follows:

         H       H

         |       |

   H3N+-CH-C-COO-

         |       |

         CH3     CH(CH3)2

Here, the NH3+ represents the positively charged amino group of valine, and the COO- represents the negatively charged carboxyl group of alanine. The hydrogen atoms (H) are attached to the appropriate positions on the carbon backbone.

Please note that this is a simplified representation, and the actual structure of the dipeptide may have different conformations depending on the specific arrangement of atoms and bonds.

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Question 19 Multiple Choice Worth 3 points)
(06.04 MC)
What forensic scientist established the 'Body Farm' to study the ways bodies decompose under different circumstances?
Matheiu Orfila
Sir Edward Henry
Phillipe Locard
Bill Bass

Answers

Answer:

The answer is D Bill Bass

Explanation:

Remember it from the lesson and I took the test.

What is the temperature of a 6.1 mole sample of He gas at 18.5 bar and volume of 115L? (Round answer to the hundredths place)

Answers

Answer:

4202.1 K

Explanation:

From;

PV=nRT

P= pressure of the gas = 18.5 bar

V = volume of the gas = 115L

n= number of moles of the gas =  6.1 mole

T= temperature of the gas = ?

R = gas constant = 0.083 L⋅bar⋅K−1⋅mol−1

T = PV/nR

T = 18.5 * 115/6.1 * 0.083

T = 2127.5/0.5063

T= 4202.1 K

Question 4
Which best describes a chemical reaction that follows the law of conservation of matter?
А
The reactants have the same mass as the products.
B
The reactants have the same density as the products.
С
The products conserve all physical properties of the reactants.
D
The products conserve all chemical properties of the reactants.

Answers

It is going to be D hope this helps

A short chain of monomer liquid not long enough to be considered a polymer is called a(n)?

a. methacrylate
b. acrylate
c. urethane
d. oligomer

Answers

Answer:

d. oligomer it is the correct answer also if you would just search that up it pops up

which chemical weathering process would you expect to have the greatest effect within the tropics?

Answers

Chemical weathering is significant in tropical rainforests as these regions experience heavy rainfall, high humidity, and high temperatures, making these regions more susceptible to chemical weathering.

Rocks become weakened and disintegrate into smaller pieces as a result of weathering, a significant physical phenomena. Physical, chemical, mechanical, and biological modalities can all be used to carry out the process. The ideal illustration of chemical weathering is acid rain.

You have likely observed that no two rocks are exactly alike in appearance. Some appear to have been sculptor-carved. Some have been hollowed out to resemble caves, while others appear to have been painted crimson.

Rocks undergo chemical weathering, or the breakdown of rocks by chemical processes, which is one of the reasons they have such a variety of appearances. You will learn about the various types of chemical weathering and how exposure to substances like water, oxygen, carbon dioxide, and acids can change the minerals found in rocks in this lesson.

We noted that one method rocks are broken down is by chemical weathering. It's crucial to stress that rocks are truly being chemically transformed rather than simply crumbling into smaller rocks because this is the actual chemical change that is occurring. To put it another way, following chemical weathering, we are left with something different from what we started with.

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Chemical weathering occurs most rapidly in which of the following climates?

a. Desert

b. Arctic tundra

c. High mountain slopes

d. Tropical rainforest

a chemical combination of two or more elements joined together in a fixed proportion​

Answers

Answer: a compound!

Explanation: a compound is something that contains two or more elements that are chemically combined in a fixed proportion!

Molecule in a pizza that is a polymer; has oxygen, hydrogen, and sulfur atoms; and is hydrophilic. what kind of molecule is?

Answers

The molecule in this pizza is a "protein" because it is already mentioned and cleared from the question that it is a polymer, hydrophilic, and it's made up of oxygen, hydrogen, and sulfur atoms.

Explanation :

Amino acid is a simple term defined as an organic chemical compound that comprises of an acidic carboxyl group (COOH), a basic amino group (NH_2NH2).

It is unique chain group.

Protein : The hydrophilic, macromolecule (polymer) that is made as a result of the unison of the chain of the many amino acids is known as Protein.

Protein normally comprises of various elements such as Oxygen (O2), Hydrogen (H2), Sulphur atoms.

Hence, it is pretty much clear from the above explanation that molecule in a pizza that is a polymer, has O2, H2 and Sulphur atoms and that is also hydrophilic is a molecule of "Protein".

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Assign the stereochemistry of the carbon (r or s) at the 17 position for 17-a-estradiol and 17-b-estradiol. what is the stereochemical relationship between the two isomers?

Answers

Stereochemistry of the carbon at the 17 position for 17-a-estradiol and 17-b-estradiol:

17-a-estradiol: The hydroxyl group at the 17 position is on the R side of the molecule.17-b-estradiol: The hydroxyl group at the 17 position is on the S side of the molecule.

What is the stereochemical relationship?

Stereochemical relationship between the two isomers:

17-a-estradiol and 17-b-estradiol are enantiomers. This means that they are mirror images of each other, and they cannot be superimposed.

A diagram of the two isomers, with the hydroxyl group at the 17 position highlighted is attached.

The 17-a-estradiol molecule is shown on the left, and the 17-b-estradiol molecule is shown on the right. The hydroxyl group at the 17 position is on the R side of the 17-a-estradiol molecule, and it is on the S side of the 17-b-estradiol molecule.

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Assign the stereochemistry of the carbon (r or s) at the 17 position for 17-a-estradiol and 17-b-estradiol.

True or false

9.Circuit breaker is used to protect the user of appliance from an electrical shock.

10.Earthing or Grounding involves attaching to the ground a conductor in one line of the circuit to make that line electrically common with the earth. *​

Answers

Answer:

1. true

2. false

Explanation:

PROMISE PROMISE to make the most of the su in the WORLD CUP and chemica are u doing the meetings with

a steel bottle contains argon gas at standard temperature and pressure. what is the final temperature if the pressure is changed to 2.76 atm?

Answers

When the pressure is changed to 2.76 atm, is approximately 754.19 Kelvin. When the pressure inside the steel bottle is changed to 2.76 atm while containing argon gas at standard temperature and pressure (STP), the final temperature of the gas will increase.

According to the ideal gas law, PV = nRT, where P is the pressure, V is the volume, n is the number of moles of gas, R is the ideal gas constant, and T is the temperature in Kelvin. Since the volume remains constant in this case, we can rearrange the equation as P₁/T₁ = P₂/T₂, where P₁ and T₁ are the initial pressure and temperature, and P₂ and T₂ are the final pressure and temperature. Given that the initial conditions are at STP, the initial temperature is 273.15 K. If we substitute the values into the equation, we get 1 atm / 273.15 K = 2.76 atm / T₂. Solving for T₂, we find T₂ = (273.15 K) * (2.76 atm / 1 atm) ≈ 754.19 K.Therefore, the final temperature of the argon gas in the steel bottle, when the pressure is changed to 2.76 atm, is approximately 754.19 Kelvin.

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Which of the following is characteristic of non-metals?
A)

They're always solids at room temperature.

B)

They're strong conductors of electricity.

C)

They tend to be denser than metals.

D)

They tend to gain electrons in chemical reactions.

Answers

Answer:

B

Explanation:

Non metals do not conduct electricity

Answer:

D.

Explanation:

I saw it in the textbook

What is the hydroxide [OH-] concentration of a solution that has a pOH of 4.90? 14 14 1.26 x10-5 1.26 x10, -5 9.1 9.1 7.94 x 104

Answers

Answer:

The hydroxide [OH-] concentration of the solution is 1.26*10⁻⁵ M.

Explanation:

The pOH (or potential OH) is a measure of the basicity or alkalinity of a solution.

POH indicates the concentration of hydroxyl ions [OH-] present in a solution and is defined as the negative logarithm of the activity of hydroxide ions (that is, the concentration of OH- ions):

pOH= -log [OH-]

A solution has a pOH of 4.90. Replacing in the definition of pOH:

4.90= -log [OH-]

Solving:

-4.90= log [OH-]

1.26*10⁻⁵ M= [OH-]

The hydroxide [OH-] concentration of the solution is 1.26*10⁻⁵ M.

Which type of weathering occurred to form the Malham Pavement

Answers

Answer:

carbonation

Explanation:Please dont delete my answer again cause its correct, I had the same question on my test so I know its righ!!!!

Read the article and answer the 6 questions in it.

Answers

Answer:

Yea.....where is the article and the 6 questions?

Answer:

Answering

Explanation:

do u want us to tell u what we got?

How do stomata help a plant maintain balance with their environment?

Answers

Stomatal pores in plants regulate the amount of water and solutes within them by opening and closing their guard cells using osmotic pressure. In order for plants to produce energy and maintain cellular function, their cells undergo the highly intricate process of photosynthesis .

need points & are good at science?

need points & are good at science?

Answers

Answer:

A

Explanation:

I believe the Correct answer would be A

What structure allows molecules to absorb in the small intestine?

Answers

Villi: The folds form numerous tiny projections which stick out into the open space inside your small intestine (or lumen), and are covered with cells that help absorb nutrients from the food that passes through. Microvilli: The cells on the villi are packed full of tiny hairlike structures called microvilli. The function of the plicae circulares, the villi, and the microvilli is to increase the amount of surface area available for the absorption of nutrients. Each villus transports nutrients to a network of capillaries and fine lymphatic vessels called lacteals close to its surface.

Answer:

I think c

Explanation:

sorry if I am wrong:(

I did not learn about this:((

how did JJ Thomson discovered the electron explain his plum pudding model of the atom​

Answers

it was in 1897 when thomson discovered the electron he did this by just experimenting with things like crooks, cathode ray, and tubes.

Is the following reaction reversible and, if so, under what conditions? CN 0 ОН NaCN HCI O Yes, under basic conditions O Yes, under acidic conditions O No O Yes, using Pd/C

Answers

The given reaction involves the conversion of CN⁻ ion to HCN. This reaction is reversible, meaning that HCN can also convert back to CN⁻ under certain conditions. The conditions under which this reaction can be reversed are dependent on the nature of the reactants and products.

In this case, the reaction involves a strong base (NaCN) and a strong acid (HCl). Therefore, the reaction will proceed to completion in either acidic or basic conditions. However, if we want to reverse the reaction, we need to change the conditions in favor of the reactants.

Under basic conditions, the reaction can be reversed by adding an acid to protonate CN⁻ to form HCN. Under acidic conditions, the reaction can be reversed by adding a base to deprotonate HCN to form CN-.

Alternatively, the reaction can also be reversed using Pd/C as a catalyst. Pd/C can facilitate the conversion of HCN to CN⁻ by promoting the addition of hydrogen gas (H₂). This reaction can occur under mild conditions, making it a useful method for reversing the reaction.

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When some solids melt, the only forces that are disrupted (broken up) are intermolecular forces. This results in relatively low melting points. An example is H2O(s), ice. What class of solid does this describe?
a. Molecular solids
b. Metallic solids
c. lonic solids
d. Covalent-network solids
e. Semiconductors

Answers

Molecular solids are made up of individual molecules held together by intermolecular forces such as van der Waals forces, dipole-dipole interactions, and hydrogen bonding. When these solids melt, only the intermolecular forces are disrupted, resulting in relatively low melting points.

In contrast, metallic solids are made up of metallic atoms held together by metallic bonding, ionic solids are made up of ions held together by ionic bonds, covalent-network solids are made up of atoms held together by covalent bonds in a giant network, and semiconductors are materials with properties between those of a conductor and an insulator. These types of solids have higher melting points because the bonds holding the atoms or ions together are stronger.

When some solids melt, the only forces disrupted are intermolecular forces, resulting in relatively low melting points. This description fits molecular solids, as they are held together by relatively weak intermolecular forces (such as hydrogen bonding in H2O(s), ice) which can be broken up more easily, leading to lower melting points. Other types of solids like metallic, ionic, and covalent-network solids have stronger bonding forces and generally higher melting points.

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Convert the following to Celsius
16) 100°K
17) 200°K
18) 273°K
19) 350°K

Answers

16) 100- 273= -173°celsius

17) -73°Celsius

18) °Celsius

19) 77°Celsius

Hi :)

16) 100°K= 100K − 273.15 = -173.1°C

17) 200°K= 200K − 273.15 = -73.15°C

18) 273°K= 273K − 273.15 = -0.15°C

19) 350°K= 350K − 273.15 = 76.85°C

Hope this helps :)

Using given data, calculate the change in Gibbs free energy for each of the following reactions. You may want to reference (Pages 831 - 832) Section 19.6 while completing this problem. Part A: 2Ag(s)+Cl2(g)→2AgCl(s) Gibbs free energy for AgCl(s) is −109.70 kJ/mol Express your answer without scientific notation and using one decimal place.(units kJ) Part B: P4O10(s)+16H2(g)→4PH3(g)+10H2O(g) Gibbs free energy for P4O10(s) is −2675.2 kJ/mol Gibbs free energy for PH3(g) is 13.4 kJ/mol Gibbs free energy for H2O(g) is −228.57 kJ/mol Express your answer without scientific notation and using one decimal place.(units kJ) Part C: CH4(g)+4F2(g)→CF4(g)+4HF(g) Gibbs free energy for CH4(g) is −50.8 kJ/mol Gibbs free energy for CF4(g) is −635.1 kJ/mol Gibbs free energy for HF(g) is −270.70 kJ/mol Express your answer without scientific notation and using one decimal place. (unitskJ) 2H2O2(l)→2H2O(l)+O2(g) Gibbs free energy for H2O2(l) is −120.4 kJ/mol Gibbs free energy for H2O(l) is −237.13 kJ/mol Express your answer without scientific notation and using one decimal place.(units kJ) Part D: 2H2O2(l)→2H2O(l)+O2(g) Gibbs free energy for H2O2(l) is −120.4 kJ/mol Gibbs free energy for H2O(l) is −237.13 kJ/mol

Answers

At 298 K, the reaction's standard free energy change is G0 = - 115 kJ. The calculated values of Go are very helpful in determining whether a reaction will take place spontaneously if the reactants and products are combined under typical circumstances.

How do you calculate the Gibbs free energy?

Standard entropy change (H°) is 50.6 kJ/mol at 25 °C, and the absolute entropies of the products and reactants are S°(N2H4) = 121.2 J/(mol•K), S°(N2) = 191.6 J/(mol•K), and S°(H2) = 130.7 J/(mol•K).

According to the Gibbs phase rule, where n is the number of thermodynamic degrees of freedom in the system, the relationship between the number of phases (p) and components (c) in a given alloy under equilibrium conditions at constant pressure is given as p+n=c+1.

The calculated values of Go are very helpful in determining whether a reaction will take place spontaneously if the reactants and products are combined under typical circumstances. The internal, kinetic, and potential energies of a system are simply added together to form the total energy E: E=me=m(u+ke+pe)=U+KE+PE.

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Which of the following statements about the elements in group 2 of the periodic table is true?

They all tend to become positive ions when they bond with other elements.
They all have similar chemical and physical properties.
They all have two electrons in their outermost shell.
They are all metals.

Answers

Answer:

they all have two electrons in their outermost shell

The elements of group 2 are alkaline earth metals that have two electrons in their outermost shell. So they have similar chemical and physical properties and tend to become positive ions in bond formation.

What are the properties of the elements of group 2?

The elements present in group 2 include Beryllium, Magnesium, Calcium, Strontium, Barium, and Radium.  

The elements of group 2 are similar in their physical and chemical properties as all the elements have the same number of valence electrons. All alkaline earth metals are silvery-white-colored solids under normal conditions. They are also shiny and quite reactive.

The general electronic configuration of group 2 elements is ns². The alkaline earth metals have fully filled s-orbital in their valence shells, they tend to lose two electrons to produce cations with +2 charge.

Therefore, the elements of group 2 are electropositive in nature. Therefore, all the given statements about group 2 of the periodic table are true.

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how is the frequency of the radiation used to determine the functional groups in the molecule?

Answers

The frequency of the radiation used in spectroscopy techniques such as infrared spectroscopy can be used to determine the functional groups present in a molecule. This is because different functional groups absorb radiation at specific frequencies, which can be identified by the instrument.

Infrared spectroscopy works by passing infrared radiation through a sample and measuring how much is absorbed at different frequencies. Each functional group has a unique pattern of absorption frequencies, allowing for the identification of specific functional groups in a molecule. For example, the presence of a carbonyl group in a molecule can be identified by a peak around 1700 cm^-1 in the infrared spectrum, while the presence of an alcohol group can be identified by a peak around 3500 cm^-1.
Other spectroscopy techniques such as nuclear magnetic resonance (NMR) can also be used to determine the functional groups present in a molecule. NMR works by measuring the magnetic properties of the nuclei in a sample, which are influenced by the chemical environment around them. This can be used to identify the types of atoms and functional groups present in a molecule.
Overall, the frequency of the radiation used in spectroscopy techniques is an important tool for identifying functional groups in molecules. By analyzing the unique absorption patterns of different functional groups, scientists can gain valuable insights into the structure and composition of complex molecules.

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