Identify the frontier orbitals in this mechanistic step by using the lists provided. HC HC C- CHE HC OF: HOMO Choose one: O pin BF3 O B-Fo* in BF3 OC-O in diethyl ether OB-Foin BF3 sp in diethyl ether O pon O in diethyl ether LUMO Choose one: O C-O o in diethyl ether O pon O in diethyl ether O sp in diethyl ether O B-Fo in BF3 O B-Fo* in BF3 O pin BF3

Answers

Answer 1

The frontier orbitals in this mechanistic step are the π bond in BF3 as the HOMO and the B-Fσ* in BF3 as the LUMO.

In the given mechanistic step, the frontier orbitals can be identified using the options provided. The Highest Occupied Molecular Orbital (HOMO) and the Lowest Unoccupied Molecular Orbital (LUMO) are the frontier orbitals.

HOMO: For this step, the HOMO is the π bond in BF3. Therefore, the correct option is "O pin BF3."

LUMO: For this step, the LUMO is the B-Fσ* (sigma antibonding orbital) in BF3. Therefore, the correct option is "O B-Fσ* in BF3."

So, the frontier orbitals in this mechanistic step are the π bond in BF3 as the HOMO and the B-Fσ* in BF3 as the LUMO.

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Related Questions

a 250 gram sample of water at the boiling point had 35.0 kj of heat added. how many grams of water were vaporized? heat of vaporization for water is 40.6 kj/mole.

Answers

The required mass of water vaporized is 15.5 grams, from a 250 gram sample of water at the boiling point had 35.0 kj

Given: Mass of water (m) = 250 gHeat added (q) = 35.0 kJHeat of vaporization (ΔHvap) = 40.6 kJ/mole

To find:Mass of water vaporized (x) Formula:q = ΔHvap × nx = (q / ΔHvap) × nMass = moles × molar mass

We know that molar mass of water (H2O) = 18 g/molMoles of water vaporized (n) = (35.0 kJ / 40.6 kJ/mol) = 0.861 mol

Therefore,Mass of water vaporized (x) = 0.861 mol × 18 g/mol= 15.5  

Detailed Solution: According to the given statement,250g of water was taken at its boiling point and 35.0 kJ of heat was added to it, we need to find how many grams of water were vaporized. To solve this question, first, we need to know the heat of vaporization for water, which is 40.6 kJ/mole. It means to vaporize 1 mole of water, 40.6 kJ of heat is required.

Mass of water (m) = 250 g Heat added (q) = 35.0 kJHeat of vaporization (ΔHvap) = 40.6 kJ/molen = q / ΔHvapn = (35.0 kJ / 40.6 kJ/mol) = 0.861 molMoles of water vaporized (n) = 0.861 mol

Therefore, Mass of water vaporized (x) = 0.861 mol × 18 g/mol= 15.5 g Hence, the required mass of water vaporized is 15.5 grams.

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How does bias in the data affect experimental results?
A. Bias makes the data harder to analyze.
B. Bias makes the results less reliable.
C. Bias makes the results easier to interpret.
D. Bias makes the results not publishable.

Answers

Answer:

B

Explanation:

Bias may make one side look worse than they actually are.

If you have bias data result, then you can’t trust on your outcome to be 100% accurate. So, your answer is B.


Hope this helps :)

which of the following is a weak acid?
A) H2SO4 (Sulfuric acid)
B) HCl (Hydrochloric acid)
C) CH3COOH (Acetic acid)
D) HNO3 (Nitric acid)
correct answer is C).

Answers

CH3COOH is the correct awnser

3) Pick the correct definition for : A signal represented by a continuous wave *-1 analog signal-2 digitized siganal-3-encode-4-transmit-5-wave pulse.

plzzzz help brainliest and 50 points

Answers

Answer:

it is analog signal, your welcome

Analog Signal is the correct answer

Hope it helps you

Which periodic trend is not explained by shielding and ENC?
O Atomic radius
O ENC does not explain any periodic trend
O ENC explains all periodic trends
O
Electronegativity

Answers

ENC explains all periodic trends

The electrostatic attraction between the positively charged nucleus and the negatively charged electrons holds electrons in an atom or ion. Due to electron shielding that exists between the electron of interest and the nucleus in multi-electron species, the electrons do not experience the full positive charge of the nucleus. The effective nuclear charge is the total positive charge that really affects an electron.

In order to comprehend periodic characteristics, it is crucial to understand the idea of effective nuclear charge (Z*). The portion of the total nuclear charge that an electron in an atom experiences is known as the effective nuclear charge. This is equal to the atomic number (Z) less the amount () by which other atoms' electrons protect the particular atom's nucleus.

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The addition polymer that has the formula shown below is used in surgical sutures, dishwasher-safe food containers, thermal underwear, and many other products.
⎛⎝HH||−C−C−||HCH3⎞⎠n
Draw one monomer unit. Show all hydrogen atoms

Answers

                  H

                  |

H--C=C--H        C       H

                  |      

                  H

This is one monomer unit of polypropylene, which is a thermoplastic polymer used in various applications such as surgical sutures, dishwasher-safe food containers, thermal underwear, and many other products.

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04. (a) Explain briefly what you understand by Corrosion penetration rate and how it is measured The rate of oxidation and how it is measured (b) Explain the following deterioration mechanism of polymetric materials; 17 marles (i) Thermal degradation 17 marks) (1) Weathering (c) In respect to corrosion, explain the consequences of; (4 marks (i) Riveting a steel plate with copper rivets (ii) Connecting buried steel pipework to zinc plates (4 marks (d) One-half of an electrochemical cell consists of a pure nickel electrode in a solution of Nid'ions, other half is a cadmium electrode immersed in a Cda solution. If the cell is a standard one, (6 marks (1) Write the spontaneous overall reaction (6 mark (ii) Calculate the voltage that is generated

Answers

(a) Corrosion Penetration Rate (CPR) is a measurement of the thickness of a material's corrosion layer in terms of linear millimeters per year. Corrosion Penetration Rate is an important parameter that is widely used in the corrosion field to estimate the corrosion rate of a metal.

The penetration rate is determined by exposing a metal sample to the corrosive environment and measuring the quantity of metal that has been lost due to corrosion over a certain period of time. The formula used to calculate CPR is: CPR = Weight loss of the sample (mg) x 31556926.0 / A x D x t Where, A= Surface area of the sample (m²), D= Density of the sample (g/cm³), t= Exposure time in seconds

(b)Deterioration mechanism of polymetric materials:

(i) Thermal degradation: It is the process in which chemical decomposition occurs when a polymer is exposed to elevated temperatures, which can result in the loss of essential properties of the polymer.

(ii) Weathering: The process by which a polymer's structure and properties are altered as a result of exposure to the natural elements is referred to as weathering.

(c) Consequences of corrosion:

(i) Riveting a steel plate with copper rivets: When riveting a steel plate with copper rivets, galvanic corrosion is caused as a result of the contact between copper and steel. The steel will corrode more quickly than it would if it were in contact with a material that is less reactive than copper.

(ii) Connecting buried steel pipework to zinc plates: Connecting buried steel pipework to zinc plates can cause galvanic corrosion. Because zinc is more reactive than steel, the zinc plate corrodes and prevents the steel pipe from corroding. As a result, the zinc plate will corrode away, leaving the steel pipe vulnerable to corrosion.

(d) One-half of an electrochemical cell consists of a pure nickel electrode in a solution of Nid'ions, other half is a cadmium electrode immersed in a Cda solution. If the cell is a standard one:

(i) Spontaneous overall reaction: Ni(s) + Cd²⁺ (aq) → Cd(s) + Ni²⁺ (aq)

(ii) The voltage generated by the cell is: E°cell = E°cathode - E°anode

E°cell = E°Cd - E°Ni

E°cell = (-0.40) - (-0.25)

E°cell = -0.15V

Therefore, the voltage generated by the cell is -0.15V.

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16. Give the names and VSEPR numbers of the geometries shown below; 180° 107 120​

Answers

180°: Linear, VSEPR number 2

107°: Trigonal bipyramidal, VSEPR number 5

120°: Trigonal planar, VSEPR number 3

What are the molecular geometries?

Molecular geometry refers to the three-dimensional arrangement of atoms in a molecule. It determines the shape of the molecule and the relative positions of its atoms in space. The molecular geometry is determined by the number of atoms and the types of bonds between them.

The concept of molecular geometry is important in chemistry because it determines the physical and chemical properties of the molecule, such as its reactivity, polarity, and biological activity.

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Which type is a metamorphic rock formed from shale?

Answers

Answer:

Slate

Slate is a foliated metamorphic rock that is formed through the metamorphism of shale. It is a low-grade metamorphic rock that splits into thin pieces.Explanation:

A 220.0 mL sample of helium gas is in a cylinder with a movable piston at 105 kPa and 275 K. The piston is
pushed in until the sample has a volume of 95.0 mL. The new temperature of the gas is 310 K. What is the new
pressure of the sample?
274 kPa
216 kPa
Piston
243 kPa
51.1 kPa


A 220.0 mL sample of helium gas is in a cylinder with a movable piston at 105 kPa and 275 K. The piston

Answers

Answer:

Explanation:

what did you get?

The nucleus contains protons and neutrons true or false?

Answers

Answer:

the answer is

it's true

Answer:

true

Explanation:

it has both neutrons (neutral) and protons (positive)

A reef which hugs the shore?

Answers

fringing reef..........

Zinc (Zn) combines with hydrogen chloride (HCI) to form
hydrogen gas (H₂) and zinc chloride (ZnCl₂).
Which equation represents this chemical reaction?
A. ZnCl₂ + Zn
B. 2HCI


H₂ + Zn + ZnCl₂
OC. ZnH₂ + ZnCl₂ + 2HCI
H₂ + 2HCI i know the answer but why is it 2HCI where does the 2 come from?

Answers

Explanation:

ZnCl\(_{2}\) + H\(_{2}\) ⇒ Zn + 2HCl

The two in 2HCl comes after balancing the equation.

The number of elements  reacting should be equal to the number of products being formed.

The left side of the equation:

ZnCl\(_{2}\) + H\(_{2}\)

has;

1 Zn

2 Cl

and 2 H

while at the right side of the equation:

Zn + HCl

We have;

1 Zn

1 Cl

1 H

Therefore, in order to balance the equation we multiply 2 with both H and Cl.

1 x 2 = 2H

1x 2 = 2Cl

Thus we get;

Zn + 2HCl

the cloudy growth seen in a broth culture is referred to as

Answers

The cloudy growth seen in a broth culture is referred to as "turbidity."

When there is an increase in bacterial growth within the culture, it causes the broth to appear cloudy, indicating the presence of a large number of microorganisms.

In microbiology, when referring to a broth culture, "turbidity" describes the cloudy appearance or growth observed within the liquid medium. It indicates the presence of microorganisms that have multiplied and dispersed throughout the broth, leading to a visible change in its optical density.

When a broth culture is inoculated with microorganisms, such as bacteria or yeast, these organisms utilize the nutrients present in the broth as a source of energy and start to grow and reproduce. As they multiply, the population of microorganisms increases, leading to an increase in cell density within the liquid medium.

The cloudiness or turbidity can be visually observed by comparing the broth culture to a blank or uninoculated control. The control should remain clear, while the turbid culture indicates the presence of actively growing microorganisms.

Turbidity in a broth culture is commonly used as an indirect measure of microbial growth. It is often quantified using instruments called spectrophotometers, which measure the absorbance or optical density of the culture at a specific wavelength of light. The more turbid the culture, the higher the absorbance value, indicating a higher microbial population.

In summary, turbidity refers to the cloudy appearance or growth observed in a broth culture due to the proliferation of microorganisms. It is an important visual indicator of microbial growth and can be quantified to provide valuable insights into the growth characteristics of the microorganisms present in the culture.

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The number of neutrons does equal the ______ minus the _______ , or number of _____

Answers

Mass minus the atomic number

6) A species of baby sea turtles are known to hatch on sandy beaches and walk
towards light source A. However, in recent years of them hatch and walk to light
source B instead. The ones that make it into the ocean to join the adult turtles
have a better chance of survival than the ones that do not. Which statement
BEST relates this scenario to Darwin's theory of evolution?

Answers

b?
I’m assuming, they are more evolved due to changing climate

4.1 moles of sodium carbonate to molecules of sodium carbonate.

Answers

Answer:

2.469×10²⁴ molecules

Explanation:

Multiply by Avogadro's Number (6.022×10²³

What is the significance of cell division?
A. to make ATP
B. to prevent replication
C. to repair and replace other cells
D. to make glucose

Answers

The answer is c) to repair and replace other cells.

Cell division is the replication of cells by dividing itself into two, it does not prevent replication. Cell division does not make glucose either and cell division does not make ATP.

What are the products of combustion of hydrocarbons and water?.

Answers

Water and carbon dioxide are the byproducts of hydrocarbon burning.

What are some examples of hydrocarbons?

A mixture of hydrocarbon is called a hydrocarbon. The hydrocarbons methane (CH4), ethane (C2H6), and ethyne are examples of (C2H2). These compounds are all hydrocarbons since their corresponding molecular formulas show that they are all solely composed of the elements hydrogen and carbon.

The biggest hydrocarbon is?

The biggest and most intricate carbon molecules are found in coal. Various hydrocarbons produce different amounts of water and carbon dioxide because their hydrogen to carbon ratios vary. The ratio of charcoal to hydrogen is typically higher in longer, more complicated molecules.

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how many of the carbons originally present in glucose continue to other reactions after glycolysis?

Answers

Only three of the carbons originally present in glucose continue to other reactions after glycolysis.

During glycolysis, which is the metabolic pathway that converts glucose into pyruvate, the six-carbon glucose molecule is converted into two three-carbon molecules of pyruvate.

More specifically, during glycolysis, glucose is phosphorylated by the enzyme hexokinase to form glucose-6-phosphate, which is then converted into fructose-6-phosphate. Fructose-6-phosphate is then cleaved into two three-carbon molecules of glyceraldehyde-3-phosphate (G3P), which are subsequently converted into pyruvate through a series of enzymatic reactions.

Since each molecule of pyruvate contains three carbons, only three of the six carbons in the original glucose molecule are present in the pyruvate molecules produced during glycolysis. These three carbons are oxidized during subsequent metabolic reactions, such as the Krebs cycle (also known as the citric acid cycle) and oxidative phosphorylation, to generate ATP and other cellular energy sources.

In summary, only three of the six carbons originally present in glucose continue to other reactions after glycolysis. These three carbons are present in the pyruvate molecules produced during glycolysis, which are subsequently oxidized during other metabolic reactions to produce ATP and other cellular energy sources.

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How do the ramp heights of the different objects compare? How does the ramp height relate to the strength of the frictional force between the book and the object?

Answers

The height of a ramp does not directly determine the strength of the frictional force between a book and an object.

How do they compare?

The strength of the frictional force between a book and an object is not directly influenced by the height of a ramp. The nature of the surfaces in contact, the force forcing the surfaces together (normal force), and the coefficient of friction are some of the variables that affect the frictional force between two surfaces.

The coefficient of friction between the book and the object plays a major role in determining the strength of the frictional force.

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Which statement correctly compares the weight and the mass of an object?

Which statement correctly compares the weight and the mass of an object?

Answers

option D !!!!!!!!!!

Answer:

Its weight changes based on location, but its mass stays the same.

Explanation:

See attached worksheet.

Which statement correctly compares the weight and the mass of an object?

14)
Hydrogen Emission Spectrum
The diagram below represents the emission spectrum of hydrogen in the visible range. The line on the left represents the
emission with the smallest wavelength.
Which of the following is the best explanation pertaining to the distribution of visible light in hydrogen's emission spectrum?

Answers

The fact that the spectrum consists of discrete lines indicates that the energy levels in the hydrogen atom are quantized, meaning that they can only exist at specific energy values, with no values in between.

What is Emission?

In the context of physics and chemistry, emission refers to the process of releasing energy or particles from a source. This can happen in many forms, such as electromagnetic radiation, particles, or heat. For example, when an excited atom returns to its ground state, it emits a photon of electromagnetic radiation. Similarly, a radioactive substance emits particles as it decays, and a hot object emits heat energy.

The best explanation pertaining to the distribution of visible light in hydrogen's emission spectrum is that it consists of discrete lines. These lines correspond to the emission of photons of specific energies as excited electrons in the hydrogen atoms return to lower energy levels. Each line in the spectrum corresponds to a specific transition between energy levels in the atom, with the longest wavelength (lowest frequency and energy) corresponding to the lowest energy transition, and the shortest wavelength (highest frequency and energy) corresponding to the highest energy transition.

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a chemist determined by measurements that 0.020 moles of tin participated in a chemical reaction. calculate the mass of tin that participated in the chemical reaction. round your answer to 2 significant digits.

Answers

Mass of tin = moles of tin x molar mass of tin

Mass of tin = 0.020 mol x 118.7 g/mol

Mass of tin = 2.37 g

Therefore, the mass of tin in the chemical reaction is 2.37 g.

What happens when you heat the tin?

If tin is heated, it cracks. This is caused by crystals rubbing against each other. This characteristic crackle is heard if a piece of tin is simply bent. Tin is very malleable and ductile.

What are some properties of Tin?

Some properties of tin is that it amphoteric. On reacting with both strong bases and strong acids with the evolution of hydrogen occurs. With sodium hydroxide solution, tin forms Na2[Sn(OH)6]. The reaction with acids is slow in the absence of oxygen.

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Describe what a phosphodiester bond connects in the double helix.

Answers

The phosphodiester bond connects for the double helix with the 3 carbon atom of the one sugar molecule and with the 5 carbon atom of the another molecule.

The phosphodiester bond links with the 3 carbon atom of the one sugar molecule and with the 5 carbon atom of the another and therefore, the name, is called as 3', 5' phosphodiester linkage. The saccharide groups that are derived from the deoxyribose in the DNA and the ribose in the RNA.

The Phosphodiesters are the negatively charged at the pH 7. The phosphodiester bond is the chemical bond that will forms when the two hydroxyl groups in the phosphoric acid will react with the other hydroxyl group on the other molecules.

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Balance the following equations

1. N2O5 -> N2O4 + O2

2. KNO3 -> KNO2 + O2

3. NH4NO2 -> N2 + H2O

4. O3 -> O2

5. Zn + AgCl -> ZnCl2 + Ag

6. NaOH + H2SO4 -> NA2SO4 + H2O

Answers

The following are the balanced chemical equations: 1). 2N2O5 -> 2N2O4 + 1O2, 2). 2KNO3 -> 2KNO2 + O2, 3). NH4NO2 -> N2 + 2H2O, 4).2O3 -> 3O2, 5). Zn + 2AgCl -> ZnCl2 + 2Ag, 6). 2NaOH + H2SO4 -> Na2SO4 + 2H2O.

Which five chemical equations are there?

Synthesis, breakdown, single replacement, doubling replacement, and combustion are the five main categories of chemical reactions. One material is created from several reactants in a composition reaction.

What are class 10 chemical equations?

A chemical equation is a symbol- and formula-based valid expression of a chemical reaction, with the reactant entities given on the left side and the resultant entities given on the right. Examples are NaOH+HClNaCl+H2O.

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Some scientists believe that the mass extinction of dinosaurs was caused by the impact of a large meteorite on Earth. This impact would have caused a darkening of the sky due to dust blown into the upper atmosphere. This darkening would have reduced the size of some ecosystem because of
A. longer seasons
B. accelerated erosion
C. reduced photosynthesis
D. increased number of hurricanes

Answers

Answer: C : reduced photosynthesis!

Answer:

C

Explanation:

The specific heat capacity of water is 1.00 cal/g °C. 700.00 cal is required to raise the temperature of 25.0g water from 22.0°C to 50°C.
What is the final temperature of the above water sample if 1.00kcal of heat is provided?

Answers

When 1.00 kcal of heat is applied, the water sample's final temperature is T = 50.0°C + 40.0°C = 90.0°C.

What does "specific heat" mean?

The amount of energy required to raise a substance's temperature is measured in terms of specific heat. It is the amount of energy (measured in joules) required to increase a substance's temperature by one degree Celsius per gram.

We must first determine the water sample's original temperature. The formula is as follows:

Q = mcΔT

Inputting the values provided yields:

700.00 cal = 25.0 g x 1.00 cal/g °C x (50°C - 22.0°C)

When we simplify this equation, we obtain:

ΔT = 700.00 cal / (25.0 g x 1.00 cal/g °C) = 28.0°C

Therefore, the initial temperature of the water sample is 22.0°C + 28.0°C = 50.0°C.

Inputting the values provided yields:

1.00 kcal = 25.0 g x 1.00 cal/g °C x (T - 50.0°C)

When we simplify this equation, we obtain:

T - 50.0°C = 1.00 kcal / (25.0 g x 1.00 cal/g °C) = 40.0°C

Therefore, When 1.00 kcal of heat is applied, the water sample's final temperature is T = 50.0°C + 40.0°C = 90.0°C.

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Describe how electron arrangements are given using Lewis structures.

Answers

Answer:

The Lewis structure indicates that each Cl atom has three pairs of electrons that are not used in bonding (called lone pairs) and one shared pair of electrons (written between the atoms). A dash (or line) is sometimes used to indicate a shared pair of electrons: A single shared pair of electrons is called a single bond.

Explanation:

An alkene X undergoes ozonolysis and gives two compounds Y and Z of molecular formula CHO. Y and Z. are functional isomers of each other Write the two-steps chemical equation for the conversion of X into Y and Z. 121 Write the structural formula of Y and 7. Why are they called functional isomers? [3] ili. What happens when hydrogen gas in the presence of nickel catalyst is passed over X? (1] TV. What is the application of ozonolysis in the organic reaction mechanism? 11 How can you prove chemically the compound X is unsaturated? [1]

Answers

The answers to the given questions are given below.

What is Ozonolysis ?

A reaction done with Ozone to determine the position of C-C double bond in unsaturated Hydrocarbons.

It is given in the question

An alkene X undergoes ozonolysis and gives two compounds Y and Z of molecular formula CHO

Y and Z. are functional isomers of each other

The two-steps chemical equation for the conversion of X into Y and Z.

\(\rm \\(CH_3)_2 -C= CH-CH_2-CH_3 + Zn - > CH_3 -CO-CH_3 + CH0-CH_2-CH_3\\\\Y \;is \;CH_3 -CO-CH_3 \\\\and \;Z \;is \;CHO-CH_2-CH_3\)

Here X is 2 methyl pent-2 eneOn reaction with ozone , ozonide is formed

                         \(\rm Y \;is \;CH_3 -CO-CH_3 \\\\and \;Z \;is \;CHO-CH_2-CH_3\)

These are functional isomers as they have same molecular weight , but different functional groups.

When hydrogen gas in the presence of nickel catalyst is passed over  2 methyl pent-2 ene

A process called catalytic Hydrogenation will take place , and the alkene will get converted into alkane , 2-methyl pentane

The ozonolysis process is useful in the pharmaceutical industry

The unsaturation can be tested  by bromine water test

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