Identify the reagents you would use to accomplish each of the following ­transformations: (a) Convert 2-methyl-2-butene into a monosubstituted alkene (b) Convert 2,3-dimethyl-1-hexene into a tetrasubstituted alkene

Answers

Answer 1

The reagents that can be used to accomplish each of the given ­transformations:

(a) To convert 2-methyl-2-butene into a monosubstituted alkene, we can use the reagent HBr (hydrogen bromide).

(b) To convert 2,3-dimethyl-1-hexene into a tetrasubstituted alkene, we can use the reagent diiodomethane (CH2I2) and a zinc-copper couple (Zn/Cu).

Explanation;

(a) To convert 2-methyl-2-butene into a monosubstituted alkene, one can use hydrohalogenation as the reaction. HBr in the presence of a peroxide, such as diethyl ether will result in the addition of a bromine atom to the less substituted carbon, producing 2-bromobutane. The bromine atom can then be removed using a strong base, such as sodium hydroxide (NaOH), resulting in the monosubstituted alkene 2-methyl-1-butene.

(b) To convert 2,3-dimethyl-1-hexene into a tetrasubstituted alkene, you can use the Simmons-Smith reaction. This reaction involves the use of diiodomethane (CH2I2) and a zinc-copper couple (Zn/Cu) as reagents. This will lead to the formation of a cyclopropane ring, which can then be dehydrohalogenated using a strong base, such as potassium tert-butoxide (t-BuOK), to yield the desired tetrasubstituted alkene.

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Related Questions


Describe the sludge generation process and propose safe methods
of disposing it.

Answers

The sludge generation process refers to the production of sewage treatment residue during wastewater treatment. Sludge contains solid and semi-solid materials that must be handled and disposed of properly to protect human health and the environment.

The following are some methods for sewage disposal:

Wastewater Treatment: Initial treatment involves the physical removal of large solids, whereas secondary treatment uses biological processes to break down organic matter and remove dissolved pollutants.

Sludge Treatment: The separated sludge is under further treatment, which may include stabilization, dewatering, and, in some cases, additional processes to reduce contaminants.

Land Application: Treated sludge can be applied to agricultural land as a fertilizer or soil conditioner if it meets regulatory guidelines and has been properly treated.

Landfills: If sludge cannot be reused or recycled, it can be disposed of in a designated landfill that meets regulatory requirements, ensuring proper containment and preventing soil and water contamination.

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How many atoms are in 1.5 moles of iron?

Answers

Answer:

One mole of anything is 6.022×1023 everythings, including atoms. Multiply the moles Fe by 6.022×1023 atoms/mol. 3.77mol Fe ×6.022×1023atoms Fe1mol Fe =2.27×1024 atoms Fe rounded to three significant figures.

The number of atoms present is 1.5 moles of iron is 9.0 ×10²³ atoms

From the question,

We are to determine the number of atoms present in 1.5 moles of iron.

From the formula,

\(Number\ of\ moles = \frac{Number\ of\ atoms}{Avogadro's\ constant}\)

Then, we can write that

Number of atoms = Number of moles × Avogadro's constant

∴ Number of atoms of iron present = 1.5 × 6.022×10²³

Number of atoms of iron present = 9.033 ×10²³ atoms

Number of atoms of iron present ≅ 9.0 ×10²³ atoms

Hence, the number of atoms present is 1.5 moles of iron is 9.0 ×10²³ atoms

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Write the expected ground-state of electron configuration for the following. a) the element with one unpaired 5p electron that forms a covalent with compound flourine.

Answers

The expected ground-state electron configuration for the element with one unpaired 5p electron that forms a covalent compound with fluorine is 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^10 4p^6 5s^2 4d^10 5p^2.

To determine the expected ground-state electron configuration, we need to consider the element with one unpaired 5p electron that forms a covalent compound with fluorine.

Since we are looking for an element with one unpaired 5p electron, we can refer to the periodic table.

The element in question is in the p-block of the periodic table, and its electron configuration can be written as:

1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^10 4p^6 5s^2 4d^10 5p^1

To determine the expected ground-state electron configuration, we need to understand that elements tend to achieve a stable configuration by filling their valence shell. In this case, the valence shell is the 5p orbital.

To form a covalent compound with fluorine, the element must gain one electron from fluorine.

This electron would occupy one of the unpaired 5p orbitals, resulting in the following electron configuration:

1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^10 4p^6 5s^2 4d^10 5p^2

Therefore, the expected ground-state electron configuration for the element with one unpaired 5p electron that forms a covalent compound with fluorine is 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^10 4p^6 5s^2 4d^10 5p^2.

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Now suppose a reaction vessel is filled with 0.0406 atm of nitrogen (N_2) and 5.97 atm of ammonia (NH_3) at 1126. Degree C. Answer the following question this system: Under these conditions, will the pressure of N_2 tend to rise or fall? rise fall Is it possible to reverse this tendency by adding H_2? In other words, if you said the pressure of N_2 will tend to rise, can that be changed to a tendency to fall adding H_2? Similarly, if you said the pressure of N_2 will tend to fall, can that be changed to a tendency to rise by adding H_2? Yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of H_2 needed to reverse it. Round your answer to 2 significant digits. atm

Answers

The pressure of \(N_{2}\) will rise under the given conditions. And, Yes, it is possible to reverse this tendency by adding \(H_{2}\). The minimum pressure of H2 required to reverse the tendency is 0.01 atm.

The reaction involved is: \(N_{2}\)(g) + 3\(H_{2}\)(g) ⇌ 2\(NH_{3}\)(g)  Hence, when \(H_{2}\) is added to the above system, the \(N_{2}\) and  \(H_{2}\)  will react to produce \(NH_{3}\). This reaction will reduce the amount of \(N_{2}\) present in the system, causing the pressure of \(N_{2}\) to decrease. Therefore, by adding \(H_{2}\)  , we can change the tendency of \(N_{2}\) pressure from rise to fall.To calculate the minimum pressure of  \(H_{2}\)  required to reverse the tendency, we have to use the equilibrium constant, Kp. The expression for Kp for the above reaction is: Kp =( \(NH_{3}\)) / p(\(N_{2}\)) p3( \(H_{2}\) )

At equilibrium, Kp = 1.7 × 104 at 1126 °C.Now, we will solve for the minimum pressure of \(H_{2}\)   needed to reverse the tendency. Let's assume that the pressure of \(N_{2}\) has increased by x atm. Therefore, the new pressure of \(N_{2}\) will be (0.0406 + x) atm. At equilibrium, we have:

p2(\(NH_{3}\) ) / p(\(N_{2}\)) p3( \(H_{2}\) ) = 1.7 × 104

On substituting the given values and simplifying, we get:

p2(\(NH_{3}\)) / p(N2) = 6.39 × 10-5

Now, p2(\(NH_{3}\)) = 5.97 atm, and p(\(N_{2}\)) = (0.0406 + x) atm.

On substituting these values, we get:5.97 / (0.0406 + x) = 6.39 × 10-5

Solving for x, we get:x = 0.00579 atm ≈ 0.01 atm (rounded to 2 significant digits)Therefore, the minimum pressure of \(H_{2}\)   required to reverse the tendency is 0.01 atm.

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What is the most important reason for using hydrates in fire extinguishers?
-They keep fire extinguishers dry during shipping and storage.
-They make fire extinguishers more affordable for household use.
-They create foams that have high water content to help extinguish fires.
-They create high pressure in the cylinder to quickly force out the fire r*tardant.

Answers

The importance of the use of hydrates in fire extinguishers are;

-They keep fire extinguishers dry during shipping and storage.

-They create foams that have high water content to help extinguish fires.

They create high pressure in the cylinder to quickly force out the fire r*tardant.

What is a fire extinguisher?

We know that a fire extinguisher has to do with any device that has been made in such a way that the device can be used to eliminate a flame that is burning. We all know that fore can be very destructive. This implies that it is important to be able to put out the fire so that it does not cause big problems.

The fire extinguisher is composed of certain chemical substances that are able to react together quickly and then be able to quench the flame of the reaction that is going on in the system.

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Convert 1.25 ug into hg

Answers

The answer is 1.25e-8.

Which symbol and unit of measurement are used for electric current?
a. symbol: C; unit: A
b. symbol: 1; unit: C
C. symbol: 1; unit: A

Answers

Answer:

C. symbol: 1; unit: A

Explanation:

The symbol and unit of electric current is given as symbol: I; unit: A

Current is one of the fundamental particles. The unit is given in Amperes which is symbolized as A. Current is given as I

According to ohms law;

   I  = \(\frac{V}{R}\)  

 I is the current

 V is the voltage

 R is the resistance.

The RNA and DNA backbone differ because the DNA sugar is missing what element? ​

The RNA and DNA backbone differ because the DNA sugar is missing what element?

Answers

Answer:

Oxygen

Explanation:

the difference between DNA and RNA is that DNA is missing one Oxygen atom.

A girl skateboards with a kinetic energy of 2543.2 j. If the girl and skateboard have a total mass of 110kg, what is her speed?

Answers

Answer:

Her speed is 6.8m/s.

Explanation:

K.E= 1/2mv²

or, 2543.2= 1/2×110×v²

or, 2543.2 = 55v²

or, 2543.2/55 = v²

or, 46.24 = v²

or, 6.8² = v²

v = 6.8 m/s

answer

6.8

explanation

k.e=1/2v^2

2543.2=55v^2

46.24=v^2

6.8^2=v^2

v=6.8

I currently just need help with this right now.

I currently just need help with this right now.

Answers

24.3 grams of magnesium is required for two moles of the product.. therefore, 356.3 grams of magnesium are required to produce 40.0 grams of boron through the reaction

Answer:

2.43 grams are needed

Explanation:

I did the test

Hope this helps :)

Which is more dense:
(b)Oxygen or air?

Answers

Answer:

I think air is more denser than oxygen

URGENT !!!!!! Which property would vary between two different- sized samples of the same substance ( meaning it is size dependent )
A. Volume
B. Solubility
C. Magnetism
D. Conductivity

Answers

Answer:

I think the answer would be A.

Explanation:

Solubility property will vary between two different- sized samples of the same substance.

What is solubility?

Solubility is a physical process in which solute particles are dissolved in the solvent substance for the formation of solution.

Solubility is related to the size of the particles as the more surface area shown by the particles more easily they will dissolve in the solvent.Volume is generally related to the liquid, but here we are talking about particles so it is not correct.Magnetism and conductivity is related to electrons not to the size.

Hence the property solubility will vary between two different- sized samples.

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How is polyethene formed?
A. None of these
B. The double bond on reactive ethene molecules breaks allowing them to bond with each other and form a chain.
C. Double bonds are very strong. This means when ethene is heated, hydrogens will be removed before the double bonds break. When ethene molecules lose hydrogens, their carbons bond with each other forming branching chains.
D. Polyethene is formed by the formation of double bonds between carbons in ethane molecules.

Answers

Answer:

c

Explanation:

because 2× is strong. hydrogen will be remove

The answer is B - The double bond on reactive ethene molecules breaks allowing them to bond with each other and form a chain.

Explanation:

Poly(ethene) is formed when several monomers of ethene (an alkene) are joined together. Ethene can take part in this type of reaction as it is has a double bond (it's unsaturated) which opens up to allow multiple monomers to form a chain. This reaction occurs when ethene is heated and put under pressure in the presence of a catalyst.

1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p2

Answers

Answer:

batqyqy6w

Explanation:

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The chemical properties of an element are determined by which
particle of an atom?
electron
b
nucleus
оооо
proton
neutron

Answers

Electron proton neutron

The chemical properties of an element are determined by which particle of an atom?

\(\longrightarrow{\green{c.\:proton}}\) 

Explanation:

The chemical properties of an element are determined by the subatomic particle known as a proton. The number of protons in an atom is called its atomic number ( Z ).

\(\large\mathfrak{{\pmb{\underline{\orange{Mystique35 }}{\orange{♡}}}}}\)

. Name something chemistry related you are interested in or interested in learning about.

Answers

Answer: How The World Works

Explanation: Our world is made out of atoms, molecules and ions. Their behavior determines the properties of the substances we encounter in our daily lives: their structure, color, smell, and the way they interact with each other.

Fischer Projections of L- and D-threonine
a. Identify the functional groups in the Fischer projection of L-threonine.

Answers

The alkyl group (R) attached to the chiral α-carbon of  L-threonine amino acid is H₃C-CH-OH. The Fischer projection of L-threonine is attached below.

What is an amino acid?

Amino acids can be defined as organic compounds that contain both amino and carboxylic acid functional groups. Most amino acids are α-amino acids, which comprise proteins.

Amino acids are divided according to the positions of the functional groups, such as alpha- (α-), beta- (β-), gamma- (γ-), or delta- (δ-) amino acids. As proteins, amino acids form 2nd largest component of human muscles and tissues.

In the structure of amino acids, R denotes a side chain attached to each amino acid. The carbon atom attached to the carboxyl group (-COO) is called the α–carbon. Amino acids with an amino group (-NH₂) attached directly to the alpha-carbon is known as α-amino acids.

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Fischer Projections of L- and D-threonine a. Identify the functional groups in the Fischer projection

What does the atomic number of an element represent?

A. number of isotopes

B. number of protons

C. number of bonds

D. number of atoms

Answers

Answer:

protons

Explanation:

btw you protons and electrons are always the same

prcAnswer:

e c. proton

Explanation:

i pueslist

atom 1 has mass=12 protons=6
atom 2 has mass=14 electrons=6
are these atoms isotopes of each other or different elements

Answers

Answer:

Atom isotopes

Explanation:

The number of protons is equal to the number of electrons in elements therefore atom 2 has 6 protons like atom 1. This means that both are the same atom but with different masses which means they are isotopes.

The atoms are isotopes.

Isotopes are atoms having the same atomic number (i.e proton) but different mass number due to the difference in the neutron number of the atoms involved.

For atom 1:

Mass number = 12

Proton = 6

For atom 2:

Mass number = 14

Proton = Electron = 6 (for neutrao atom)

From the above, we can see that atom 1 and atom 2 have the same number of protons but different mass number.

Therefore, we can conclude that the atoms are isotopes

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Please help me with this

Please help me with this

Answers

323.5g - 301.2g = 22.3g is the change in mass.

1. State the properties of matter in the liquid state.

Answers

Answer:

Liquids take the shape of their container, they are one of the three stages in between a solid and a gas. A liquids particles are not in a fixed position like a solids, nor do they move as freely as a gas.

Calculate the percentage by mass of nitrogen in magnesium nitrate. You will need the information below. Give your answer to the nearest whole percentage (e.g. 34%).

Calculate the percentage by mass of nitrogen in magnesium nitrate. You will need the information below.

Answers

From the calculations, the percentage by mass of the nitrogen is 18.9 %..

What is the percentage by mass?

The term percentage by mass refers to the mass of an atom that is contained in a compound.

Hence, the compound magnesium nitrate has the formula Mg(NO3)2. The molar mass of the compound is 24 + 2(14 + 3(16)) = 148 g/mol.

The percentage by mass of nitrogen is; 28/ 148  * 100/1 = 18.9 %.

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If 30.0 ml of 0.20 M ethanol solution reacts with 1.80 g potassium permanganate, what will be the final pH of the solution

Answers

The final pH of the solution is 2. 72

How to determine the final pH

CH3CH2OH + KMnO4 ---> CH3COOH + MnO2

Mole of ethanol= Concentration * Volume = 0.20 * 30/100 = 6.0 *10-3mole

Molar mass of ethanol= 46g/mol

Mass of ethanol= mole * molar mass = 6 * 10-3 * 46 = 0.276g

Mass of KMnO4= 1.08g

Molar mass of KMnO4= 158g/mol

Molar mass of ethanoic acid formed = 60g/mol

Let's determine the limiting reagent

158g of KMnO4 reacts with 46g of ethanol

1.08g of KMnO4 should react with 46/158 * 1.08 = 0.314g of ethanol

With 0.276g of Ethanol is present, it is said to be the limiting reagent

46g of ethanol yields 60g/mol of ethanoic acid

Then, 0.276g of ethanol will yield = 60 * 0.276 /46 = 0.36g

Mole of ethanoic acid= 0.36/60= 6.0 * 10-3mole

To find the concentration of ethanoic acid= mole/volume

= 6.0 * 10-3/0.03 = 0.20M

Ionization of ethanoic acid will give;

CH3COOH ------> CH3COO- + H+

Ka= 1.8 * 10-5

Then, equilibrium concentrations will be

[CH3COOH] = 0.20-x

[CH3COO-] = x

[H+] = x

Then ,Ka= [CH3COO-][H+]/[CH3COOH]

Substitute values into the equilibrium equation

1.8 * 10-5 = x²/0.20-x

Ethanoic acid is a weak acid, so 0.20-x is approximately 0.20

x²= 0.20 * 1.8 * 10-5

x= 1.9 * 10-3

[H+] = 1.9 * 10-3M

To find the pH, use the formula;

pH= -log[H+]

Substitute the value of H+

pH= -log[1.9 x 10-3]

pH= 2.72

Therefore, the final pH of the solution is 2. 72

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What is the general trend for electron affinity values going across a period?

Answers

Answer:

increase.

Explanation:

as you cross the period the atomic size decrease makes the atoms to have more affinity to the coming electrons.

What is the molar mass of H2CO3

Answers

Answer:

Molar mass of H2CO3 : 62.03 g/mol

62.03 g/mol is the molar mas of H2CO3

Is phosphorus and chlorine polar or nonpolar?

Answers

Both phosphorus and chlorine are non-polar because the four atoms of phosphorus (P4) cancel each other out and remain non-polar, while the two atoms of chlorine (Cl2) exert equal but opposite forces on one another and cancel each other out.

All four phosphorus atoms are connected to one another in the tetraphosphorus molecule shown below. Each phosphorus atom shares the same properties, which results in an identical electronegativity. Tetraphosphorus is hence nonpolar since each phosphorus atom's electron attraction in the two opposite directions is the same, canceling out one another.

The shared pair of electrons in a chlorine molecule (Cl2) is equally attracted by the two chlorine atoms, resulting in a nonpolar bond. as a result, chlorine is non-polar molecule.

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explain a mixture of molecules

Answers

Answer:

A mixture of molecules is a group of molecules in which there are multiple different elements and atoms, that are in either fixed proportions or random. There are heterogeneous and homogenous mixtures.

Explanation:

HELP PLS LIST BINARY IONIC COMPOUNDS (THE MORE THE BETTER) THANK U​

Answers

Answer:

Aluminum Flouride

Copper (II) Sulphide

Lithium Sulfide

imagine you have a stock of pml104-grna that is 100 ng/ul. it is determined that we will add 375 ng of plasmid to each yeast transformation. so, for your transformations that need pml104-grna, what volume of your plasmid stock will you add to the yeast?

Answers

To add 375 ng of the pml104-gran plasmid to the yeast transformation, we need to add 3.75 ul of the plasmid stock to the transformation mixture.

To determine the volume of plasmid stock to add to the yeast transformation, we first need to calculate how many microliters of the stock contain 375 ng of the plasmid.

We can use the following formula:
Volume (in microliters) = Mass (in ng) / Concentration (in ng/ul)

Plugging in the values, we get:
Volume = 375 ng / 100 ng/ul
Volume = 3.75 ul

It is important to note that plasmids are circular DNA molecules that are often used as vectors in genetic engineering experiments. They can be replicated independently of the chromosomal DNA in the host cell and are commonly used for cloning and gene expression studies. Yeast is a popular organism for genetic engineering due to its ease of manipulation and well-characterized genetic systems.

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Which two elements would be most likely to have chemical and physical properties similar to those of chlorine (Cl)? A. F and Br B. F and Ar C. S and Ar D. P and S

Answers

Answer:

A

Explanation:

Florine F and Bromine Br these two elements have same physical and chemical properties. Hence option A is correct.

What is Atom ?

Atom is smallest entity of a body. Body is made up of atoms. it is basic building block of a body. An atom consist of electrons, protons and neutrons as sub atomic particle. whole mass of the atom is concentrated at the center of the atom which we call it as nucleus, nucleus consist of proton and neutron. Electron revolve around the nucleus at determined(fixed) orbit. Total number of protons in the atom decides the atomic number and  the elements in the periodic table.

The electrons which are completely filled orbitals are called as core shell electrons and which are not filled completely are called as valence electron. valence electrons are responsible for physical and chemical properties of the element. Elements which are on same column in periodic table have same number of valence electrons . Hence they have same properties.

Chlorine, Florine and bromine comes in halogen group. it require only one electron to complete its Octet rule. chemical and physical properties are decided by the valence electron of the element. As Florine and Bromine has same valence electron as chlorine. their properties also likely to be same.

Hence option A is correct.

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A science teacher needs up to 15 female and male students for a competition. The science teacher needs at least 6 male volunteers.Let x represent the number of male volunteers and y represent the number of female volunteers.Which inequalities model the situation? Question 30 of 56Is this relation a function? Justify your answer help????????????????? compare the packing efficiency of face-centered cubic gold and face-centered cubic sodium chloride considering all the atoms. As of June 30, Year 1, the bank statement showed an ending balance of $17,410. The unadjusted Cash account balance was $16,447. The following information is available: 1. Deposit in transit: $2,920. 2. Credit memo in bank statement for interest earned in June: $18. 3. Outstanding check: $3,870. 4. Debit memo for service charge: $5. Required a. Determine the true cash balance by preparing a bank reconciliation as of June 30, Year 1, using the preceding information. b. Record in general journal format the adjusting entries necessary to correct the unadjusted book balance. According to the article, there are 3,000 brown tree snakes in Guam per square mile (mi2). The average high school in the United States is approximately 121,000 square feet or 0.004 square miles. According to these numbers, how many brown tree snakes would be found in an area the size of a typical U.S. high school? On what date did Lincoln first win the presidency Which of the following statements is no True?A) the square root of 112 is between 10 and 11B) the square root of 180 is between 13 and 14C) the square root of 12 is between 4 and 5D) the square root of 5 is between 2 and 3 HELP PLSSSSelect all of the expression that represent the same quantity as 3(n + 6).A 3n + 6 B 3n + 18 C 10 + 3n + 8 D 2n + 2 + n + 4 E 4(n + 6) - (n -6) F 4(n+6) + (n+6) a stock has a beta of 1.1. the market risk premium is 6% and the risk-free rate is 3%. what is the required return for the stock according to the capm? A noun is changed or added to by aO A. adjectiveOB. conjunctionO C. articleOD. adverb Sound travels about 340 m/s. The function d(t)=340t gives the distance d(t), in meters, that sound travels in t seconds. How far does sound travel in 53 s? a patient has been diagnosed with primary emphysema but claims there is no history of smoking. what action by the healthcare professional is most appropriate? may you be bless if you help me The expression CaCO3 CaO + CO2 is an example of a How does the government do this goal? Give examples. Michelle plans on raising $80 for her softball team. To raise the money, she is selling team shirts for $10 each.So far she has raised $20. To calculate how many more shirts she needs to sell, Michelle subtracts 20 from 80and then divides by 10.Which of the equations below can be solved using the same steps?A. 10.0 + 20 = 80B. 200 + 10 = 80C. 80.0 - 200 = 10 D. 102 + 20= 80 what were the regional differences (sectionalism) in the united states during this time period and how did they impact the missouri compromise Classify the actions based on how they could affect a reaction rate. Rate increases Rate decreases Rate is unaffected ______________ _______________ ___________- decrease the surface area of a solid reactant- decrease the concentration of a reactant - add a catalyst - increase the temperature What is an important tool to remember when trying to achieve communication competence?